N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide

In the title compound, C(27)H(27)Cl(2)N(7)O(4)S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyrid­yl)meth­yl]imidazolidin-2-yl­idene groups cause the 2-chloro­benzoyl group and the benzyol group to be...

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Detalles Bibliográficos
Autores principales: Shang, Jian, Wang, Qing-min, Huang, Run-qiu, Chen, Li, Gao, Jianhua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969858/
https://www.ncbi.nlm.nih.gov/pubmed/21577543
http://dx.doi.org/10.1107/S1600536809028943
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author Shang, Jian
Wang, Qing-min
Huang, Run-qiu
Chen, Li
Gao, Jianhua
author_facet Shang, Jian
Wang, Qing-min
Huang, Run-qiu
Chen, Li
Gao, Jianhua
author_sort Shang, Jian
collection PubMed
description In the title compound, C(27)H(27)Cl(2)N(7)O(4)S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyrid­yl)meth­yl]imidazolidin-2-yl­idene groups cause the 2-chloro­benzoyl group and the benzyol group to be directed away from one another, forming a dihedral angle of 60.62 (17)°. The central N—N bond adopts a gauche conformation with a C—N—N—C torsion angle of −79.1 (2)°.
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spelling pubmed-29698582010-12-30 N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide Shang, Jian Wang, Qing-min Huang, Run-qiu Chen, Li Gao, Jianhua Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(27)Cl(2)N(7)O(4)S, the amide groups bearing the N—S group and the tert-butyl group have s–trans conformations. The steric size of the tert-butyl and [(6-chloro-3-pyrid­yl)meth­yl]imidazolidin-2-yl­idene groups cause the 2-chloro­benzoyl group and the benzyol group to be directed away from one another, forming a dihedral angle of 60.62 (17)°. The central N—N bond adopts a gauche conformation with a C—N—N—C torsion angle of −79.1 (2)°. International Union of Crystallography 2009-08-12 /pmc/articles/PMC2969858/ /pubmed/21577543 http://dx.doi.org/10.1107/S1600536809028943 Text en © Shang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shang, Jian
Wang, Qing-min
Huang, Run-qiu
Chen, Li
Gao, Jianhua
N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title_full N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title_fullStr N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title_full_unstemmed N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title_short N′-Benzoyl-N-tert-butyl-2-chloro-N′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
title_sort n′-benzoyl-n-tert-butyl-2-chloro-n′-{[3-(6-chloro-3-pyrid­ylmethyl)-2-nitrimino­imidazolidin-1-yl]sulfan­yl}benzo­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969858/
https://www.ncbi.nlm.nih.gov/pubmed/21577543
http://dx.doi.org/10.1107/S1600536809028943
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