1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate

in the title compound, C(16)H(15)N(2) (+)·PF(6) (−), a precursor of N-heterocyclic carbene, the phenyl and benzyl rings are twisted away from the central imidazolium ring system, making dihedral angles of 70.30 (8) and 32.03 (10)°, respectively. The crystal structure is stabilized by C—H⋯F hydrogen...

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Detalles Bibliográficos
Autor principal: Jiang, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969867/
https://www.ncbi.nlm.nih.gov/pubmed/21577583
http://dx.doi.org/10.1107/S1600536809031584
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author Jiang, Ping
author_facet Jiang, Ping
author_sort Jiang, Ping
collection PubMed
description in the title compound, C(16)H(15)N(2) (+)·PF(6) (−), a precursor of N-heterocyclic carbene, the phenyl and benzyl rings are twisted away from the central imidazolium ring system, making dihedral angles of 70.30 (8) and 32.03 (10)°, respectively. The crystal structure is stabilized by C—H⋯F hydrogen bonds. Furthermore, P—F⋯π inter­actions involving imidazolium rings are observed [F⋯π = 2.9857 (16), P⋯π = 4.1630 (16) Å, P—F⋯π = 127.92 (6)°].
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spelling pubmed-29698672010-12-30 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate Jiang, Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers in the title compound, C(16)H(15)N(2) (+)·PF(6) (−), a precursor of N-heterocyclic carbene, the phenyl and benzyl rings are twisted away from the central imidazolium ring system, making dihedral angles of 70.30 (8) and 32.03 (10)°, respectively. The crystal structure is stabilized by C—H⋯F hydrogen bonds. Furthermore, P—F⋯π inter­actions involving imidazolium rings are observed [F⋯π = 2.9857 (16), P⋯π = 4.1630 (16) Å, P—F⋯π = 127.92 (6)°]. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969867/ /pubmed/21577583 http://dx.doi.org/10.1107/S1600536809031584 Text en © Ping Jiang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jiang, Ping
1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title_full 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title_fullStr 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title_full_unstemmed 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title_short 1-Benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
title_sort 1-benzyl-3-phenyl­imidazolium hexa­fluoro­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969867/
https://www.ncbi.nlm.nih.gov/pubmed/21577583
http://dx.doi.org/10.1107/S1600536809031584
work_keys_str_mv AT jiangping 1benzyl3phenylimidazoliumhexafluorophosphate

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