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Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate

In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the...

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Detalles Bibliográficos
Autores principales: Vikneswaran, M. R., Teoh, Siang Guan, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969868/
https://www.ncbi.nlm.nih.gov/pubmed/21577394
http://dx.doi.org/10.1107/S1600536809030086
Descripción
Sumario:In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol­ecule is linked to three ferrocene groups via inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. The crystal structure is further consolidated by C—H⋯π inter­actions.