Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate

In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the...

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Autores principales: Vikneswaran, M. R., Teoh, Siang Guan, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969868/
https://www.ncbi.nlm.nih.gov/pubmed/21577394
http://dx.doi.org/10.1107/S1600536809030086
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author Vikneswaran, M. R.
Teoh, Siang Guan
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Vikneswaran, M. R.
Teoh, Siang Guan
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Vikneswaran, M. R.
collection PubMed
description In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol­ecule is linked to three ferrocene groups via inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. The crystal structure is further consolidated by C—H⋯π inter­actions.
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spelling pubmed-29698682010-12-30 Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate Vikneswaran, M. R. Teoh, Siang Guan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo­penta­dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol­ecule is linked to three ferrocene groups via inter­molecular O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. The crystal structure is further consolidated by C—H⋯π inter­actions. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969868/ /pubmed/21577394 http://dx.doi.org/10.1107/S1600536809030086 Text en © Vikneswaran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vikneswaran, M. R.
Teoh, Siang Guan
Quah, Ching Kheng
Fun, Hoong-Kun
Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title_full Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title_fullStr Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title_full_unstemmed Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title_short Bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) N (1),S)zinc(II) methanol solvate
title_sort bis(ferrocenecarbaldehyde 4-methyl­thio­semicarbazonato-κ(2) n (1),s)zinc(ii) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969868/
https://www.ncbi.nlm.nih.gov/pubmed/21577394
http://dx.doi.org/10.1107/S1600536809030086
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