1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine

Crystals of the title compound, C(10)H(13)N(3)O(2), were obtained from a condensation reaction of butan-2-one and 1-(2-nitro­phen­yl)hydrazine. The mol­ecule exhibits a nearly coplanar structure, except for the methyl and methyl­ene H atoms, the largest deviations from the mean plane defined by all...

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Detalles Bibliográficos
Autores principales: Qian, Heng-yu, Yin, Zhi-gang, Yao, Zhi-qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969877/
https://www.ncbi.nlm.nih.gov/pubmed/21577564
http://dx.doi.org/10.1107/S1600536809031420
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author Qian, Heng-yu
Yin, Zhi-gang
Yao, Zhi-qiang
author_facet Qian, Heng-yu
Yin, Zhi-gang
Yao, Zhi-qiang
author_sort Qian, Heng-yu
collection PubMed
description Crystals of the title compound, C(10)H(13)N(3)O(2), were obtained from a condensation reaction of butan-2-one and 1-(2-nitro­phen­yl)hydrazine. The mol­ecule exhibits a nearly coplanar structure, except for the methyl and methyl­ene H atoms, the largest deviations from the mean plane defined by all non-H atoms, except for the nitro group, being 0.120 (2) Å for one of the nitro O atoms. Intra­molecular N—H⋯O hydrogen bonding helps to establish the mol­ecular configuration.
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spelling pubmed-29698772010-12-30 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine Qian, Heng-yu Yin, Zhi-gang Yao, Zhi-qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(10)H(13)N(3)O(2), were obtained from a condensation reaction of butan-2-one and 1-(2-nitro­phen­yl)hydrazine. The mol­ecule exhibits a nearly coplanar structure, except for the methyl and methyl­ene H atoms, the largest deviations from the mean plane defined by all non-H atoms, except for the nitro group, being 0.120 (2) Å for one of the nitro O atoms. Intra­molecular N—H⋯O hydrogen bonding helps to establish the mol­ecular configuration. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2969877/ /pubmed/21577564 http://dx.doi.org/10.1107/S1600536809031420 Text en © Qian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qian, Heng-yu
Yin, Zhi-gang
Yao, Zhi-qiang
1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title_full 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title_fullStr 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title_full_unstemmed 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title_short 1-(Butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
title_sort 1-(butan-2-yl­idene)-2-(2-nitro­phen­yl)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969877/
https://www.ncbi.nlm.nih.gov/pubmed/21577564
http://dx.doi.org/10.1107/S1600536809031420
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AT yinzhigang 1butan2ylidene22nitrophenylhydrazine
AT yaozhiqiang 1butan2ylidene22nitrophenylhydrazine

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