Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate

In the title compound, [Mg(C(12)H(8)N(2))(2)(H(2)O)(2)][Cr(2)O(7)]·2C(12)H(8)N(2), the cation and anion are situated on a twofold rotation axis. The Mg(II) ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water mol­ecules in a distorted octa­he...

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Autores principales: Liu, Hai-Xing, Dong, Gui-Ying, Ma, Zhi-Hong, Cui, Guang-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969879/
https://www.ncbi.nlm.nih.gov/pubmed/21577393
http://dx.doi.org/10.1107/S1600536809030128
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author Liu, Hai-Xing
Dong, Gui-Ying
Ma, Zhi-Hong
Cui, Guang-Hua
author_facet Liu, Hai-Xing
Dong, Gui-Ying
Ma, Zhi-Hong
Cui, Guang-Hua
author_sort Liu, Hai-Xing
collection PubMed
description In the title compound, [Mg(C(12)H(8)N(2))(2)(H(2)O)(2)][Cr(2)O(7)]·2C(12)H(8)N(2), the cation and anion are situated on a twofold rotation axis. The Mg(II) ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water mol­ecules in a distorted octa­hedral geometry. Inter­molecular O—H⋯N and O—H⋯O hydrogen bonds and π–π inter­actions between the aromatic rings [shortest centroid–centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent mol­ecules into a hydrogen-bonded cluster.
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spelling pubmed-29698792010-12-30 Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate Liu, Hai-Xing Dong, Gui-Ying Ma, Zhi-Hong Cui, Guang-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mg(C(12)H(8)N(2))(2)(H(2)O)(2)][Cr(2)O(7)]·2C(12)H(8)N(2), the cation and anion are situated on a twofold rotation axis. The Mg(II) ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water mol­ecules in a distorted octa­hedral geometry. Inter­molecular O—H⋯N and O—H⋯O hydrogen bonds and π–π inter­actions between the aromatic rings [shortest centroid–centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent mol­ecules into a hydrogen-bonded cluster. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969879/ /pubmed/21577393 http://dx.doi.org/10.1107/S1600536809030128 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hai-Xing
Dong, Gui-Ying
Ma, Zhi-Hong
Cui, Guang-Hua
Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_full Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_fullStr Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_full_unstemmed Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_short Diaqua­bis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_sort diaqua­bis(1,10-phenanthroline)magnesium dichromate(vi) 1,10-phenanthroline disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969879/
https://www.ncbi.nlm.nih.gov/pubmed/21577393
http://dx.doi.org/10.1107/S1600536809030128
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