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catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitroisophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyrid...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969884/ https://www.ncbi.nlm.nih.gov/pubmed/21577434 http://dx.doi.org/10.1107/S1600536809031821 |
| Sumario: | In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitroisophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methylene C atoms are situated on twofold rotation axes. The chains are oriented parallel to the c axis, and stack into a supramolecular three-dimensional structure through O—H⋯O hydrogen-bonding interactions. |
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