Cargando…

catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]

In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitro­isophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyrid...

Descripción completa

Detalles Bibliográficos
Autores principales: Sposato, Laura K., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969884/
https://www.ncbi.nlm.nih.gov/pubmed/21577434
http://dx.doi.org/10.1107/S1600536809031821
_version_ 1782190285019676672
author Sposato, Laura K.
LaDuca, Robert L.
author_facet Sposato, Laura K.
LaDuca, Robert L.
author_sort Sposato, Laura K.
collection PubMed
description In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitro­isophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methyl­ene C atoms are situated on twofold rotation axes. The chains are oriented parallel to the c axis, and stack into a supra­molecular three-dimensional structure through O—H⋯O hydrogen-bonding inter­actions.
format Text
id pubmed-2969884
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29698842010-12-30 catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] Sposato, Laura K. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitro­isophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methyl­ene C atoms are situated on twofold rotation axes. The chains are oriented parallel to the c axis, and stack into a supra­molecular three-dimensional structure through O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969884/ /pubmed/21577434 http://dx.doi.org/10.1107/S1600536809031821 Text en © Sposato and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sposato, Laura K.
LaDuca, Robert L.
catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_full catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_fullStr catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_full_unstemmed catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_short catena-Poly[[bis­(3-carb­oxy-5-nitro­benzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_sort catena-poly[[bis­(3-carb­oxy-5-nitro­benzoato-κo (1))copper(ii)]-μ-1,3-di-4-pyridylpropane-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969884/
https://www.ncbi.nlm.nih.gov/pubmed/21577434
http://dx.doi.org/10.1107/S1600536809031821
work_keys_str_mv AT sposatolaurak catenapolybis3carboxy5nitrobenzoatoko1copperiim13di4pyridylpropanek2nn
AT laducarobertl catenapolybis3carboxy5nitrobenzoatoko1copperiim13di4pyridylpropanek2nn