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catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitroisophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyrid...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969884/ https://www.ncbi.nlm.nih.gov/pubmed/21577434 http://dx.doi.org/10.1107/S1600536809031821 |
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author | Sposato, Laura K. LaDuca, Robert L. |
author_facet | Sposato, Laura K. LaDuca, Robert L. |
author_sort | Sposato, Laura K. |
collection | PubMed |
description | In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitroisophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methylene C atoms are situated on twofold rotation axes. The chains are oriented parallel to the c axis, and stack into a supramolecular three-dimensional structure through O—H⋯O hydrogen-bonding interactions. |
format | Text |
id | pubmed-2969884 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29698842010-12-30 catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] Sposato, Laura K. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(4)NO(6))(2)(C(13)H(14)N(2))](n), the square-planar coordinated Cu(II) ion lies on an inversion centre and is coordinated by two protonated 5-nitroisophthalate ligands. The Cu(II) ions are linked into a one-dimensional coordination polymer by tethering 1,3-di-4-pyridylpropane ligands, whose central methylene C atoms are situated on twofold rotation axes. The chains are oriented parallel to the c axis, and stack into a supramolecular three-dimensional structure through O—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969884/ /pubmed/21577434 http://dx.doi.org/10.1107/S1600536809031821 Text en © Sposato and LaDuca 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sposato, Laura K. LaDuca, Robert L. catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO (1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] |
title |
catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO
(1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] |
title_full |
catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO
(1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] |
title_fullStr |
catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO
(1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] |
title_full_unstemmed |
catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO
(1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] |
title_short |
catena-Poly[[bis(3-carboxy-5-nitrobenzoato-κO
(1))copper(II)]-μ-1,3-di-4-pyridylpropane-κ(2)
N:N′] |
title_sort | catena-poly[[bis(3-carboxy-5-nitrobenzoato-κo
(1))copper(ii)]-μ-1,3-di-4-pyridylpropane-κ(2)
n:n′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969884/ https://www.ncbi.nlm.nih.gov/pubmed/21577434 http://dx.doi.org/10.1107/S1600536809031821 |
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