Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)

In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa­hedral CdN(4)Cl(2) coordination geometry. There is a π–π stacking inter­action between the symmetry-related 1,10-phenanthroline ligands with a centroid–centroid distance of...

Descripción completa

Detalles Bibliográficos
Autor principal: Li, Hong Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969892/
https://www.ncbi.nlm.nih.gov/pubmed/21577483
http://dx.doi.org/10.1107/S1600536809032358
_version_ 1782190287215394816
author Li, Hong Liang
author_facet Li, Hong Liang
author_sort Li, Hong Liang
collection PubMed
description In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa­hedral CdN(4)Cl(2) coordination geometry. There is a π–π stacking inter­action between the symmetry-related 1,10-phenanthroline ligands with a centroid–centroid distance of 3.5578 (16) Å and a perpendicular distance of 3.445 (su?) Å between the relevant rings.
format Text
id pubmed-2969892
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29698922010-12-30 Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II) Li, Hong Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(14)H(13)N(3))(2)], the Cd(II) ion lies on a twofold rotation axis and assumes a distorted octa­hedral CdN(4)Cl(2) coordination geometry. There is a π–π stacking inter­action between the symmetry-related 1,10-phenanthroline ligands with a centroid–centroid distance of 3.5578 (16) Å and a perpendicular distance of 3.445 (su?) Å between the relevant rings. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2969892/ /pubmed/21577483 http://dx.doi.org/10.1107/S1600536809032358 Text en © Hong Liang Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong Liang
Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title_full Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title_fullStr Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title_full_unstemmed Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title_short Dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(II)
title_sort dichloridobis(2-dimethyl­amino-1,10-phenanthroline)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969892/
https://www.ncbi.nlm.nih.gov/pubmed/21577483
http://dx.doi.org/10.1107/S1600536809032358
work_keys_str_mv AT lihongliang dichloridobis2dimethylamino110phenanthrolinecadmiumii

Ejemplares similares