Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]

In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr—O coordination from tetra­dentate oxalate ligands forms a t...

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Detalles Bibliográficos
Autores principales: Yang, Ting-Hai, Chen, Qiang, Zhuang, Wei, Wang, Zhe, Yue, Bang-Yi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969896/
https://www.ncbi.nlm.nih.gov/pubmed/21577485
http://dx.doi.org/10.1107/S1600536809033947
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author Yang, Ting-Hai
Chen, Qiang
Zhuang, Wei
Wang, Zhe
Yue, Bang-Yi
author_facet Yang, Ting-Hai
Chen, Qiang
Zhuang, Wei
Wang, Zhe
Yue, Bang-Yi
author_sort Yang, Ting-Hai
collection PubMed
description In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr—O coordination from tetra­dentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water mol­ecule occupying space in small voids and being secured by O—H⋯O hydrogen bonding as an acceptor from ligand water H atoms and as a donor to oxalate O-acceptor sites.
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spelling pubmed-29698962010-12-30 Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate] Yang, Ting-Hai Chen, Qiang Zhuang, Wei Wang, Zhe Yue, Bang-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Pr(C(2)O(4))(1.5)(H(2)O)(2)]·H(2)O}(n), the Pr(III) ion, which lies on a crystallographic inversion centre, is coordinated by seven O atoms from four oxalate ligands and two O atoms from two water ligands; further Pr—O coordination from tetra­dentate oxalate ligands forms a three-dimensional structure. The compound crystallized as a monohydrate, the water mol­ecule occupying space in small voids and being secured by O—H⋯O hydrogen bonding as an acceptor from ligand water H atoms and as a donor to oxalate O-acceptor sites. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2969896/ /pubmed/21577485 http://dx.doi.org/10.1107/S1600536809033947 Text en © Yang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ting-Hai
Chen, Qiang
Zhuang, Wei
Wang, Zhe
Yue, Bang-Yi
Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title_full Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title_fullStr Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title_full_unstemmed Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title_short Poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(III)] monohydrate]
title_sort poly[[diaqua­hemi-μ(4)-oxalato-μ(2)-oxalato-praseodymium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969896/
https://www.ncbi.nlm.nih.gov/pubmed/21577485
http://dx.doi.org/10.1107/S1600536809033947
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