Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate

In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL (2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra­hedral (τ(...

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Detalles Bibliográficos
Autores principales: Onuegbu, Jonathan, Butcher, Ray J., Hosten, Charles, Udeochu, Uche Charles, Bakare, Oladapo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969900/
https://www.ncbi.nlm.nih.gov/pubmed/21577462
http://dx.doi.org/10.1107/S160053680903222X
Descripción
Sumario:In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL (2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra­hedral (τ(4) = 0.546). The crystal structure is consolidated by weak C—H⋯O(phendione) and C—H⋯F(BF(4) (−)) inter­actions. The BF(4) (−) counter-anion is strongly disordered and was modelled with two sets of idealized F atoms.

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