Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate

In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL (2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra­hedral (τ(...

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Autores principales: Onuegbu, Jonathan, Butcher, Ray J., Hosten, Charles, Udeochu, Uche Charles, Bakare, Oladapo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969900/
https://www.ncbi.nlm.nih.gov/pubmed/21577462
http://dx.doi.org/10.1107/S160053680903222X
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author Onuegbu, Jonathan
Butcher, Ray J.
Hosten, Charles
Udeochu, Uche Charles
Bakare, Oladapo
author_facet Onuegbu, Jonathan
Butcher, Ray J.
Hosten, Charles
Udeochu, Uche Charles
Bakare, Oladapo
author_sort Onuegbu, Jonathan
collection PubMed
description In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL (2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra­hedral (τ(4) = 0.546). The crystal structure is consolidated by weak C—H⋯O(phendione) and C—H⋯F(BF(4) (−)) inter­actions. The BF(4) (−) counter-anion is strongly disordered and was modelled with two sets of idealized F atoms.
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spelling pubmed-29699002010-12-30 Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate Onuegbu, Jonathan Butcher, Ray J. Hosten, Charles Udeochu, Uche Charles Bakare, Oladapo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Ag(C(12)H(6)N(2)O(2))(2)]BF(4) or [AgL (2)]BF(4) (L = phendione), the Ag and B atoms are located on twofold rotation axes. The dihedral angle between the two phendione ligands is 36.7 (2)°. The coordination about the Ag(I) center is distorted tetra­hedral (τ(4) = 0.546). The crystal structure is consolidated by weak C—H⋯O(phendione) and C—H⋯F(BF(4) (−)) inter­actions. The BF(4) (−) counter-anion is strongly disordered and was modelled with two sets of idealized F atoms. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2969900/ /pubmed/21577462 http://dx.doi.org/10.1107/S160053680903222X Text en © Onuegbu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Onuegbu, Jonathan
Butcher, Ray J.
Hosten, Charles
Udeochu, Uche Charles
Bakare, Oladapo
Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title_full Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title_fullStr Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title_full_unstemmed Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title_short Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) tetra­fluoridoborate
title_sort bis(1,10-phenanthroline-5,6-dione-κ(2) n,n′)silver(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969900/
https://www.ncbi.nlm.nih.gov/pubmed/21577462
http://dx.doi.org/10.1107/S160053680903222X
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