{μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate

The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia­zol-2-yl)hydrazonometh­yl]-6-methoxy­phenol ligands, a methanol mol­ecule and a nitrate ion. Both Cu(II) centres are penta­coordinated in a distorted square-p...

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Detalles Bibliográficos
Autores principales: Lin, Yu-Ching, Hong, Fung-E
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969907/
https://www.ncbi.nlm.nih.gov/pubmed/21577431
http://dx.doi.org/10.1107/S1600536809031705
Descripción
Sumario:The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia­zol-2-yl)hydrazonometh­yl]-6-methoxy­phenol ligands, a methanol mol­ecule and a nitrate ion. Both Cu(II) centres are penta­coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.

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