{μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate

The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia­zol-2-yl)hydrazonometh­yl]-6-methoxy­phenol ligands, a methanol mol­ecule and a nitrate ion. Both Cu(II) centres are penta­coordinated in a distorted square-p...

Descripción completa

Detalles Bibliográficos
Autores principales: Lin, Yu-Ching, Hong, Fung-E
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969907/
https://www.ncbi.nlm.nih.gov/pubmed/21577431
http://dx.doi.org/10.1107/S1600536809031705
_version_ 1782190291623608320
author Lin, Yu-Ching
Hong, Fung-E
author_facet Lin, Yu-Ching
Hong, Fung-E
author_sort Lin, Yu-Ching
collection PubMed
description The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia­zol-2-yl)hydrazonometh­yl]-6-methoxy­phenol ligands, a methanol mol­ecule and a nitrate ion. Both Cu(II) centres are penta­coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.
format Text
id pubmed-2969907
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29699072010-12-30 {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate Lin, Yu-Ching Hong, Fung-E Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia­zol-2-yl)hydrazonometh­yl]-6-methoxy­phenol ligands, a methanol mol­ecule and a nitrate ion. Both Cu(II) centres are penta­coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2969907/ /pubmed/21577431 http://dx.doi.org/10.1107/S1600536809031705 Text en © Lin and Hong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Yu-Ching
Hong, Fung-E
{μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title_full {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title_fullStr {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title_full_unstemmed {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title_short {μ-2-[(Benzothia­zol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxy­phenolato-1:2κ(3) O (1),O (6):O (1)}{2-[(benzo­thia­zol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxy­phenolato-1κO (1)}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
title_sort {μ-2-[(benzothia­zol-2-yl-2κn)hydrazonomethyl-2κn]-6-methoxy­phenolato-1:2κ(3) o (1),o (6):o (1)}{2-[(benzo­thia­zol-2-yl-1κn)hydrazonomethyl-1κn]-6-methoxy­phenolato-1κo (1)}(methanol-2κo)(nitrato-2κo)dicopper(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969907/
https://www.ncbi.nlm.nih.gov/pubmed/21577431
http://dx.doi.org/10.1107/S1600536809031705
work_keys_str_mv AT linyuching m2benzothiazol2yl2knhydrazonomethyl2kn6methoxyphenolato12k3o1o6o12benzothiazol2yl1knhydrazonomethyl1kn6methoxyphenolato1ko1methanol2konitrato2kodicopperiinitrate
AT hongfunge m2benzothiazol2yl2knhydrazonomethyl2kn6methoxyphenolato12k3o1o6o12benzothiazol2yl1knhydrazonomethyl1kn6methoxyphenolato1ko1methanol2konitrato2kodicopperiinitrate

Ejemplares similares