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N′-[(3-Methyl-2-thien­yl)carbon­yl]isonicotinohydrazide

In the title compound, C(12)H(11)N(3)O(2)S, the pyridine ring is inclined to the thio­phene ring, forming a dihedral angle of 34.96 (7)°. The mean plane through the hydrazide unit forms dihedral angles of 21.57 (8) and 53.08 (8)°, respectively, with the pyridine and thio­phene rings. The two O atoms...

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Detalles Bibliográficos
Autores principales: Naveenkumar, H. S., Sadikun, Amirin, Ibrahim, Pazilah, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969908/
https://www.ncbi.nlm.nih.gov/pubmed/21577634
http://dx.doi.org/10.1107/S1600536809033030
Descripción
Sumario:In the title compound, C(12)H(11)N(3)O(2)S, the pyridine ring is inclined to the thio­phene ring, forming a dihedral angle of 34.96 (7)°. The mean plane through the hydrazide unit forms dihedral angles of 21.57 (8) and 53.08 (8)°, respectively, with the pyridine and thio­phene rings. The two O atoms are twisted away from each other, as indicated by the C—N—N—C torsion angle of −81.27 (15)°. In the crystal structure, mol­ecules are linked into an extended three-dimensional network by inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds. The crystal structure also features a short S⋯O [3.2686 (10) Å] inter­action and a weak inter­molecular C—H⋯π inter­action.