Tris(dibenzoyl­methanido-κ(2) O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]gadolinium(III)

In the title compound, [Gd(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the Gd(III) atom is coordinated by six O atoms from three β-diketonate ligands and two N atoms from a chiral ligand L(S),(S)-(+)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­iso­quinoline, in a coordination geometry best...

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Detalles Bibliográficos
Autores principales: Li, Xi-Li, He, Lai-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969912/
https://www.ncbi.nlm.nih.gov/pubmed/21577411
http://dx.doi.org/10.1107/S1600536809030700
Descripción
Sumario:In the title compound, [Gd(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the Gd(III) atom is coordinated by six O atoms from three β-diketonate ligands and two N atoms from a chiral ligand L(S),(S)-(+)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­iso­quinoline, in a coordination geometry best described as distorted square-anti­prismatic.

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