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Tris(dibenzoylmethanido-κ(2) O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2) N,N′]gadolinium(III)
In the title compound, [Gd(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the Gd(III) atom is coordinated by six O atoms from three β-diketonate ligands and two N atoms from a chiral ligand L(S),(S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline, in a coordination geometry best...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969912/ https://www.ncbi.nlm.nih.gov/pubmed/21577411 http://dx.doi.org/10.1107/S1600536809030700 |
| _version_ | 1782190293241561088 |
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| author | Li, Xi-Li He, Lai-Fu |
| author_facet | Li, Xi-Li He, Lai-Fu |
| author_sort | Li, Xi-Li |
| collection | PubMed |
| description | In the title compound, [Gd(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the Gd(III) atom is coordinated by six O atoms from three β-diketonate ligands and two N atoms from a chiral ligand L(S),(S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline, in a coordination geometry best described as distorted square-antiprismatic. |
| format | Text |
| id | pubmed-2969912 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29699122010-12-30 Tris(dibenzoylmethanido-κ(2) O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2) N,N′]gadolinium(III) Li, Xi-Li He, Lai-Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Gd(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the Gd(III) atom is coordinated by six O atoms from three β-diketonate ligands and two N atoms from a chiral ligand L(S),(S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline, in a coordination geometry best described as distorted square-antiprismatic. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969912/ /pubmed/21577411 http://dx.doi.org/10.1107/S1600536809030700 Text en © Li and He 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xi-Li He, Lai-Fu Tris(dibenzoylmethanido-κ(2) O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2) N,N′]gadolinium(III) |
| title | Tris(dibenzoylmethanido-κ(2)
O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
N,N′]gadolinium(III) |
| title_full | Tris(dibenzoylmethanido-κ(2)
O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
N,N′]gadolinium(III) |
| title_fullStr | Tris(dibenzoylmethanido-κ(2)
O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
N,N′]gadolinium(III) |
| title_full_unstemmed | Tris(dibenzoylmethanido-κ(2)
O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
N,N′]gadolinium(III) |
| title_short | Tris(dibenzoylmethanido-κ(2)
O,O′)[(6S,8S)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
N,N′]gadolinium(III) |
| title_sort | tris(dibenzoylmethanido-κ(2)
o,o′)[(6s,8s)-(+)-7,7-dimethyl-3-(2-pyridyl)-5,6,7,8-tetrahydro-6,8-methanoisoquinoline-κ(2)
n,n′]gadolinium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969912/ https://www.ncbi.nlm.nih.gov/pubmed/21577411 http://dx.doi.org/10.1107/S1600536809030700 |
| work_keys_str_mv | AT lixili trisdibenzoylmethanidok2oo6s8s77dimethyl32pyridyl5678tetrahydro68methanoisoquinolinek2nngadoliniumiii AT helaifu trisdibenzoylmethanidok2oo6s8s77dimethyl32pyridyl5678tetrahydro68methanoisoquinolinek2nngadoliniumiii |