2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione

The benzyl ring of the title compound, C(17)H(15)NO(4), is twisted away from the plane defined by five atoms of the dioxane ring by 34.83 (4)°. The dioxane ring exhibits a half-boat conformation, with the C atom between the dioxane O atoms 0.571 (8) Å out of the plane through the remainder of the ri...

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Detalles Bibliográficos
Autores principales: Li, Zhi, Li, Rui, Ding, Zhen-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969915/
https://www.ncbi.nlm.nih.gov/pubmed/21577681
http://dx.doi.org/10.1107/S1600536809033984
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author Li, Zhi
Li, Rui
Ding, Zhen-Yu
author_facet Li, Zhi
Li, Rui
Ding, Zhen-Yu
author_sort Li, Zhi
collection PubMed
description The benzyl ring of the title compound, C(17)H(15)NO(4), is twisted away from the plane defined by five atoms of the dioxane ring by 34.83 (4)°. The dioxane ring exhibits a half-boat conformation, with the C atom between the dioxane O atoms 0.571 (8) Å out of the plane through the remainder of the ring. An intra­molecular N—H⋯O hydrogen bond may contribute to the stabilization of the planar conformation of the mol­ecule. In the crystal, inversion dimers linked by pairs of C—H⋯O bonds occur.
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spelling pubmed-29699152010-12-30 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione Li, Zhi Li, Rui Ding, Zhen-Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzyl ring of the title compound, C(17)H(15)NO(4), is twisted away from the plane defined by five atoms of the dioxane ring by 34.83 (4)°. The dioxane ring exhibits a half-boat conformation, with the C atom between the dioxane O atoms 0.571 (8) Å out of the plane through the remainder of the ring. An intra­molecular N—H⋯O hydrogen bond may contribute to the stabilization of the planar conformation of the mol­ecule. In the crystal, inversion dimers linked by pairs of C—H⋯O bonds occur. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2969915/ /pubmed/21577681 http://dx.doi.org/10.1107/S1600536809033984 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhi
Li, Rui
Ding, Zhen-Yu
2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_full 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_fullStr 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_full_unstemmed 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_short 2,2-Dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
title_sort 2,2-dimethyl-5-(1-naphthyl­amino­methyl­ene)-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969915/
https://www.ncbi.nlm.nih.gov/pubmed/21577681
http://dx.doi.org/10.1107/S1600536809033984
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AT lirui 22dimethyl51naphthylaminomethylene13dioxane46dione
AT dingzhenyu 22dimethyl51naphthylaminomethylene13dioxane46dione

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