Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate

In the title compound, C(17)H(17)ClO(4), the dihedral angle between the mean planes of the two benzene rings is 65.92 (5)°. The methyl ester group lies within the ring plane [deviations of O atoms from the plane = −0.051 (2) and 0.151 (2) Å] due to an intra­molecular O—H⋯O hydrogen bond. In the crys...

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Detalles Bibliográficos
Autores principales: Adeel, Muhammad, Ali, Irshad, Langer, Peter, Villinger, Alexander
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969919/
https://www.ncbi.nlm.nih.gov/pubmed/21577582
http://dx.doi.org/10.1107/S1600536809031614
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author Adeel, Muhammad
Ali, Irshad
Langer, Peter
Villinger, Alexander
author_facet Adeel, Muhammad
Ali, Irshad
Langer, Peter
Villinger, Alexander
author_sort Adeel, Muhammad
collection PubMed
description In the title compound, C(17)H(17)ClO(4), the dihedral angle between the mean planes of the two benzene rings is 65.92 (5)°. The methyl ester group lies within the ring plane [deviations of O atoms from the plane = −0.051 (2) and 0.151 (2) Å] due to an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are held together by rather weak non-classical inter­molecular C—H⋯O hydrogen bonds, resulting in dimeric units about inversion centers, forming eight- and ten-membered ring systems as R (2) (2)(8) and R (2) (2)(10) motifs.
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spelling pubmed-29699192010-12-30 Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate Adeel, Muhammad Ali, Irshad Langer, Peter Villinger, Alexander Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(17)ClO(4), the dihedral angle between the mean planes of the two benzene rings is 65.92 (5)°. The methyl ester group lies within the ring plane [deviations of O atoms from the plane = −0.051 (2) and 0.151 (2) Å] due to an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are held together by rather weak non-classical inter­molecular C—H⋯O hydrogen bonds, resulting in dimeric units about inversion centers, forming eight- and ten-membered ring systems as R (2) (2)(8) and R (2) (2)(10) motifs. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969919/ /pubmed/21577582 http://dx.doi.org/10.1107/S1600536809031614 Text en © Adeel et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Adeel, Muhammad
Ali, Irshad
Langer, Peter
Villinger, Alexander
Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title_full Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title_fullStr Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title_full_unstemmed Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title_short Methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
title_sort methyl 5-chloro-2-hydr­oxy-3-(4-methoxy­phen­yl)-4,6-dimethyl­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969919/
https://www.ncbi.nlm.nih.gov/pubmed/21577582
http://dx.doi.org/10.1107/S1600536809031614
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AT villingeralexander methyl5chloro2hydroxy34methoxyphenyl46dimethylbenzoate

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