7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate

In the racemic title compound, C(34)H(22)Br(2)N(2)S·CDCl(3), pairs of diquinoline host mol­ecules form centrosymmetric brick-like dimers utilizing three different aryl edge-to-face inter­actions (EF(1–3)). The dimeric (EF)(6) (i.e. 2 × EF(1–3)) building blocks pack with the deuterochloro­form guest...

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Detalles Bibliográficos
Autores principales: Chan, Isa Y. H., Bishop, Roger, Craig, Donald C., Bhadbhade, Mohan M., Scudder, Marcia L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969924/
https://www.ncbi.nlm.nih.gov/pubmed/21577650
http://dx.doi.org/10.1107/S1600536809032978
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author Chan, Isa Y. H.
Bishop, Roger
Craig, Donald C.
Bhadbhade, Mohan M.
Scudder, Marcia L.
author_facet Chan, Isa Y. H.
Bishop, Roger
Craig, Donald C.
Bhadbhade, Mohan M.
Scudder, Marcia L.
author_sort Chan, Isa Y. H.
collection PubMed
description In the racemic title compound, C(34)H(22)Br(2)N(2)S·CDCl(3), pairs of diquinoline host mol­ecules form centrosymmetric brick-like dimers utilizing three different aryl edge-to-face inter­actions (EF(1–3)). The dimeric (EF)(6) (i.e. 2 × EF(1–3)) building blocks pack with the deuterochloro­form guest mol­ecules positioned near each of their corners. The Cl atoms of the latter are disordered over two sets of sites in a 0.53 (2):0.47 (2) ratio.
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spelling pubmed-29699242010-12-30 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate Chan, Isa Y. H. Bishop, Roger Craig, Donald C. Bhadbhade, Mohan M. Scudder, Marcia L. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic title compound, C(34)H(22)Br(2)N(2)S·CDCl(3), pairs of diquinoline host mol­ecules form centrosymmetric brick-like dimers utilizing three different aryl edge-to-face inter­actions (EF(1–3)). The dimeric (EF)(6) (i.e. 2 × EF(1–3)) building blocks pack with the deuterochloro­form guest mol­ecules positioned near each of their corners. The Cl atoms of the latter are disordered over two sets of sites in a 0.53 (2):0.47 (2) ratio. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969924/ /pubmed/21577650 http://dx.doi.org/10.1107/S1600536809032978 Text en © Chan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chan, Isa Y. H.
Bishop, Roger
Craig, Donald C.
Bhadbhade, Mohan M.
Scudder, Marcia L.
7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title_full 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title_fullStr 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title_full_unstemmed 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title_short 7α,15α-Dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
title_sort 7α,15α-dibromo-8,16-diphenyl-6,7,14,15-tetra­hydro-6α,14α-epithio­cyclo­octa­[1,2-b:5,6-b′]diquinoline deuterochloro­form solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969924/
https://www.ncbi.nlm.nih.gov/pubmed/21577650
http://dx.doi.org/10.1107/S1600536809032978
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