Melaminium 2,4,6-trihydroxy­benzoate dihydrate

In the title compound, C(3)H(7)N(6) (+)·C(7)H(5)O(5) (−)·2H(2)O, the melaminium and benzoate ions are approximately planar (r.m.s. deviation of the non-hydrogen atoms is 0.093 Å) and there is a strong C (2) (2)(8) hydrogen-bonding embrace between them. The centre of symmetry generates a second acid–...

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Detalles Bibliográficos
Autores principales: Prior, Timothy J, Goch, Osman, Kift, Rebecca L
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969927/
https://www.ncbi.nlm.nih.gov/pubmed/21577544
http://dx.doi.org/10.1107/S1600536809031055
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author Prior, Timothy J
Goch, Osman
Kift, Rebecca L
author_facet Prior, Timothy J
Goch, Osman
Kift, Rebecca L
author_sort Prior, Timothy J
collection PubMed
description In the title compound, C(3)H(7)N(6) (+)·C(7)H(5)O(5) (−)·2H(2)O, the melaminium and benzoate ions are approximately planar (r.m.s. deviation of the non-hydrogen atoms is 0.093 Å) and there is a strong C (2) (2)(8) hydrogen-bonding embrace between them. The centre of symmetry generates a second acid–base pair which is bound to the first by a C (2) (2)(8) (N—H⋯N) embrace common between melamine mol­ecules in similar compounds. Further extensive hydrogen bonding assembles the components into a three-dimensional hydrogen-bonded network.
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spelling pubmed-29699272010-12-30 Melaminium 2,4,6-trihydroxy­benzoate dihydrate Prior, Timothy J Goch, Osman Kift, Rebecca L Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(3)H(7)N(6) (+)·C(7)H(5)O(5) (−)·2H(2)O, the melaminium and benzoate ions are approximately planar (r.m.s. deviation of the non-hydrogen atoms is 0.093 Å) and there is a strong C (2) (2)(8) hydrogen-bonding embrace between them. The centre of symmetry generates a second acid–base pair which is bound to the first by a C (2) (2)(8) (N—H⋯N) embrace common between melamine mol­ecules in similar compounds. Further extensive hydrogen bonding assembles the components into a three-dimensional hydrogen-bonded network. International Union of Crystallography 2009-08-12 /pmc/articles/PMC2969927/ /pubmed/21577544 http://dx.doi.org/10.1107/S1600536809031055 Text en © Prior et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prior, Timothy J
Goch, Osman
Kift, Rebecca L
Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title_full Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title_fullStr Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title_full_unstemmed Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title_short Melaminium 2,4,6-trihydroxy­benzoate dihydrate
title_sort melaminium 2,4,6-trihydroxy­benzoate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969927/
https://www.ncbi.nlm.nih.gov/pubmed/21577544
http://dx.doi.org/10.1107/S1600536809031055
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AT gochosman melaminium246trihydroxybenzoatedihydrate
AT kiftrebeccal melaminium246trihydroxybenzoatedihydrate

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