Cargando…
4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione
In the title compound, C(21)H(23)FN(4)S, the benzene rings of the isobutylphenyl and fluorobenzene units form dihedral angles of 75.89 (7) and 13.26 (7)°, respectively, with the triazole ring. An intramolecular C—H⋯S hydrogen-bonding contact generates an S(6) ring motif. In the crystal packing, p...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969932/ https://www.ncbi.nlm.nih.gov/pubmed/21577498 http://dx.doi.org/10.1107/S160053680903030X |
| _version_ | 1782190299450179584 |
|---|---|
| author | Fun, Hoong-Kun Loh, Wan-Sin Vinayaka, A. C. Kalluraya, B. |
| author_facet | Fun, Hoong-Kun Loh, Wan-Sin Vinayaka, A. C. Kalluraya, B. |
| author_sort | Fun, Hoong-Kun |
| collection | PubMed |
| description | In the title compound, C(21)H(23)FN(4)S, the benzene rings of the isobutylphenyl and fluorobenzene units form dihedral angles of 75.89 (7) and 13.26 (7)°, respectively, with the triazole ring. An intramolecular C—H⋯S hydrogen-bonding contact generates an S(6) ring motif. In the crystal packing, pairs of N—H⋯S hydrogen bonds link neighbouring molecules into inversion dimers, forming R (2) (2)(8) ring motifs. The crystal structure is further stabilized by C—H⋯π interactions. |
| format | Text |
| id | pubmed-2969932 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29699322010-12-30 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione Fun, Hoong-Kun Loh, Wan-Sin Vinayaka, A. C. Kalluraya, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)FN(4)S, the benzene rings of the isobutylphenyl and fluorobenzene units form dihedral angles of 75.89 (7) and 13.26 (7)°, respectively, with the triazole ring. An intramolecular C—H⋯S hydrogen-bonding contact generates an S(6) ring motif. In the crystal packing, pairs of N—H⋯S hydrogen bonds link neighbouring molecules into inversion dimers, forming R (2) (2)(8) ring motifs. The crystal structure is further stabilized by C—H⋯π interactions. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969932/ /pubmed/21577498 http://dx.doi.org/10.1107/S160053680903030X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Fun, Hoong-Kun Loh, Wan-Sin Vinayaka, A. C. Kalluraya, B. 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title | 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title_full | 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title_fullStr | 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title_full_unstemmed | 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title_short | 4-[(4-Fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1H-1,2,4-triazole-5(4H)-thione |
| title_sort | 4-[(4-fluorobenzylidene)amino]-3-[1-(4-isobutylphenyl)ethyl]-1h-1,2,4-triazole-5(4h)-thione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969932/ https://www.ncbi.nlm.nih.gov/pubmed/21577498 http://dx.doi.org/10.1107/S160053680903030X |
| work_keys_str_mv | AT funhoongkun 44fluorobenzylideneamino314isobutylphenylethyl1h124triazole54hthione AT lohwansin 44fluorobenzylideneamino314isobutylphenylethyl1h124triazole54hthione AT vinayakaac 44fluorobenzylideneamino314isobutylphenylethyl1h124triazole54hthione AT kallurayab 44fluorobenzylideneamino314isobutylphenylethyl1h124triazole54hthione |