Cargando…

Poly[diaqua­(μ(2)-oxalato-κ(4) O (1),O (2):O (1′),O (2′))(μ(2)-pyrazine-2-carboxyl­ato-κ(4) N (1),O:O,O′)neodymium(III)]

In the title complex, [Nd(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the Nd(III) atom is ten-coordinated by one N atom and three O atoms from two pyrazine-2-carboxyl­ate ligands, four O atoms from two oxalate ligands and two water mol­ecules in a distorted bicapped square-anti­prismatic geometry. Th...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Ke-Chun, Luo, Huan-Mian, Meng, Qiu-Hui, Luo, Yi-Fan, Zeng, Rong-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969933/
https://www.ncbi.nlm.nih.gov/pubmed/21577423
http://dx.doi.org/10.1107/S1600536809031250
Descripción
Sumario:In the title complex, [Nd(C(5)H(3)N(2)O(2))(C(2)O(4))(H(2)O)(2)](n), the Nd(III) atom is ten-coordinated by one N atom and three O atoms from two pyrazine-2-carboxyl­ate ligands, four O atoms from two oxalate ligands and two water mol­ecules in a distorted bicapped square-anti­prismatic geometry. The two crystallographically independent oxalate ligands, each lying on an inversion center, act as bridging ligands, linking Nd atoms into an extended zigzag chain. Neighboring chains are linked by the pyrazine-2-carboxyl­ate ligands into a two-dimensional layerlike network in the (10[Image: see text]) plane. The layers are further connected by O—H⋯O and O—H⋯N hydrogen bonds, forming a three-dimensional supra­molecular network.