[3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid

In the title compound, C(13)H(11)BBrFO(3), the dioxy­boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra­molecular O—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Kacprzak, Kinga, Klis, Tomasz, Serwatowski, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969934/
https://www.ncbi.nlm.nih.gov/pubmed/21577647
http://dx.doi.org/10.1107/S1600536809033376
Descripción
Sumario:In the title compound, C(13)H(11)BBrFO(3), the dioxy­boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra­molecular O—H⋯O hydrogen-bonding inter­action. The second OH group is involved in inter­molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio.

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