[3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid

In the title compound, C(13)H(11)BBrFO(3), the dioxy­boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra­molecular O—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Kacprzak, Kinga, Klis, Tomasz, Serwatowski, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969934/
https://www.ncbi.nlm.nih.gov/pubmed/21577647
http://dx.doi.org/10.1107/S1600536809033376
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author Kacprzak, Kinga
Klis, Tomasz
Serwatowski, Janusz
author_facet Kacprzak, Kinga
Klis, Tomasz
Serwatowski, Janusz
author_sort Kacprzak, Kinga
collection PubMed
description In the title compound, C(13)H(11)BBrFO(3), the dioxy­boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra­molecular O—H⋯O hydrogen-bonding inter­action. The second OH group is involved in inter­molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio.
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spelling pubmed-29699342010-12-30 [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid Kacprzak, Kinga Klis, Tomasz Serwatowski, Janusz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(11)BBrFO(3), the dioxy­boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra­molecular O—H⋯O hydrogen-bonding inter­action. The second OH group is involved in inter­molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969934/ /pubmed/21577647 http://dx.doi.org/10.1107/S1600536809033376 Text en © Kacprzak et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kacprzak, Kinga
Klis, Tomasz
Serwatowski, Janusz
[3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title_full [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title_fullStr [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title_full_unstemmed [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title_short [3-Bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
title_sort [3-bromo-2-(3-fluoro­benz­yloxy)phen­yl]boronic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969934/
https://www.ncbi.nlm.nih.gov/pubmed/21577647
http://dx.doi.org/10.1107/S1600536809033376
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AT klistomasz 3bromo23fluorobenzyloxyphenylboronicacid
AT serwatowskijanusz 3bromo23fluorobenzyloxyphenylboronicacid

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