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Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate

In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxy­phenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6)...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Reddy, B. Palakshi, Sarveswari, S., Vijayakumar, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969936/
https://www.ncbi.nlm.nih.gov/pubmed/21577645
http://dx.doi.org/10.1107/S160053680903339X
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author Fun, Hoong-Kun
Goh, Jia Hao
Reddy, B. Palakshi
Sarveswari, S.
Vijayakumar, V.
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Reddy, B. Palakshi
Sarveswari, S.
Vijayakumar, V.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxy­phenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, neighbouring mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are inter­connected into two-dimensional networks parallel to the ab plane by C—H⋯O hydrogen bonds. The structure is further stabilized by weak C—H⋯π inter­actions.
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spelling pubmed-29699362010-12-30 Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate Fun, Hoong-Kun Goh, Jia Hao Reddy, B. Palakshi Sarveswari, S. Vijayakumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxy­phenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, neighbouring mol­ecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are inter­connected into two-dimensional networks parallel to the ab plane by C—H⋯O hydrogen bonds. The structure is further stabilized by weak C—H⋯π inter­actions. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969936/ /pubmed/21577645 http://dx.doi.org/10.1107/S160053680903339X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Reddy, B. Palakshi
Sarveswari, S.
Vijayakumar, V.
Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_full Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_fullStr Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_full_unstemmed Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_short Diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_sort diethyl 4-(4-ethoxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969936/
https://www.ncbi.nlm.nih.gov/pubmed/21577645
http://dx.doi.org/10.1107/S160053680903339X
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