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Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate
In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxyphenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intramolecular C—H⋯O hydrogen bond generates an S(6)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969936/ https://www.ncbi.nlm.nih.gov/pubmed/21577645 http://dx.doi.org/10.1107/S160053680903339X |
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author | Fun, Hoong-Kun Goh, Jia Hao Reddy, B. Palakshi Sarveswari, S. Vijayakumar, V. |
author_facet | Fun, Hoong-Kun Goh, Jia Hao Reddy, B. Palakshi Sarveswari, S. Vijayakumar, V. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxyphenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, neighbouring molecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are interconnected into two-dimensional networks parallel to the ab plane by C—H⋯O hydrogen bonds. The structure is further stabilized by weak C—H⋯π interactions. |
format | Text |
id | pubmed-2969936 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29699362010-12-30 Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate Fun, Hoong-Kun Goh, Jia Hao Reddy, B. Palakshi Sarveswari, S. Vijayakumar, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(27)NO(5), the dihydropyridine ring adopts a boat conformation. The ethoxyphenyl ring is oriented approximately perpendicular to the planar part of the dihydropyridine ring, making a dihedral angle of 89.45 (6)°. An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, neighbouring molecules are linked into chains along the a axis by N—H⋯O hydrogen bonds and the chains are interconnected into two-dimensional networks parallel to the ab plane by C—H⋯O hydrogen bonds. The structure is further stabilized by weak C—H⋯π interactions. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969936/ /pubmed/21577645 http://dx.doi.org/10.1107/S160053680903339X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Goh, Jia Hao Reddy, B. Palakshi Sarveswari, S. Vijayakumar, V. Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title | Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title_full | Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title_fullStr | Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title_full_unstemmed | Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title_short | Diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
title_sort | diethyl 4-(4-ethoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969936/ https://www.ncbi.nlm.nih.gov/pubmed/21577645 http://dx.doi.org/10.1107/S160053680903339X |
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