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(1,10-Phenanthroline-κ(2) N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate
The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/ https://www.ncbi.nlm.nih.gov/pubmed/21577447 http://dx.doi.org/10.1107/S1600536809032097 |
Sumario: | The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenylphosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an intermolecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoromethanesulfonate anion. |
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