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(1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate

The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl­phosphine ligand. The phenanthroline ligand and...

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Detalles Bibliográficos
Autores principales: Wu, Jie-Qiang, Jin, Qiong-Hua, Hu, Ke-Yi, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/
https://www.ncbi.nlm.nih.gov/pubmed/21577447
http://dx.doi.org/10.1107/S1600536809032097
Descripción
Sumario:The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl­phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl­phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter­molecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoro­methane­sulfonate anion.