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(1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate

The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl­phosphine ligand. The phenanthroline ligand and...

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Detalles Bibliográficos
Autores principales: Wu, Jie-Qiang, Jin, Qiong-Hua, Hu, Ke-Yi, Zhang, Cun-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/
https://www.ncbi.nlm.nih.gov/pubmed/21577447
http://dx.doi.org/10.1107/S1600536809032097
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author Wu, Jie-Qiang
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
author_facet Wu, Jie-Qiang
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
author_sort Wu, Jie-Qiang
collection PubMed
description The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl­phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl­phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter­molecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoro­methane­sulfonate anion.
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spelling pubmed-29699382010-12-30 (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate Wu, Jie-Qiang Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl­phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl­phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter­molecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoro­methane­sulfonate anion. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969938/ /pubmed/21577447 http://dx.doi.org/10.1107/S1600536809032097 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Jie-Qiang
Jin, Qiong-Hua
Hu, Ke-Yi
Zhang, Cun-Lin
(1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title_full (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title_fullStr (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title_full_unstemmed (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title_short (1,10-Phenanthroline-κ(2) N,N′)(triphenyl­phosphine-κP)silver(I) trifluoro­methane­sulfonate
title_sort (1,10-phenanthroline-κ(2) n,n′)(triphenyl­phosphine-κp)silver(i) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/
https://www.ncbi.nlm.nih.gov/pubmed/21577447
http://dx.doi.org/10.1107/S1600536809032097
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