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(1,10-Phenanthroline-κ(2) N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate
The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/ https://www.ncbi.nlm.nih.gov/pubmed/21577447 http://dx.doi.org/10.1107/S1600536809032097 |
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author | Wu, Jie-Qiang Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin |
author_facet | Wu, Jie-Qiang Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin |
author_sort | Wu, Jie-Qiang |
collection | PubMed |
description | The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenylphosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an intermolecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoromethanesulfonate anion. |
format | Text |
id | pubmed-2969938 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29699382010-12-30 (1,10-Phenanthroline-κ(2) N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate Wu, Jie-Qiang Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal–planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenylphosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenylphosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an intermolecular C—H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoromethanesulfonate anion. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969938/ /pubmed/21577447 http://dx.doi.org/10.1107/S1600536809032097 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Jie-Qiang Jin, Qiong-Hua Hu, Ke-Yi Zhang, Cun-Lin (1,10-Phenanthroline-κ(2) N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title | (1,10-Phenanthroline-κ(2)
N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title_full | (1,10-Phenanthroline-κ(2)
N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title_fullStr | (1,10-Phenanthroline-κ(2)
N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title_full_unstemmed | (1,10-Phenanthroline-κ(2)
N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title_short | (1,10-Phenanthroline-κ(2)
N,N′)(triphenylphosphine-κP)silver(I) trifluoromethanesulfonate |
title_sort | (1,10-phenanthroline-κ(2)
n,n′)(triphenylphosphine-κp)silver(i) trifluoromethanesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969938/ https://www.ncbi.nlm.nih.gov/pubmed/21577447 http://dx.doi.org/10.1107/S1600536809032097 |
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