Cargando…
Bis(4-amino-3,5-di-2-pyridyl-1,2,4-triazole-κ(2) N (1),N (5))diaquazinc(II) dinitrate
The asymmetric unit of the title compound, [Zn(C(12)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2), contains one-half of the complex molecule and one NO(3) (−) anion. The Zn(II) ion displays a distorted tetragonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969943/ https://www.ncbi.nlm.nih.gov/pubmed/21577453 http://dx.doi.org/10.1107/S1600536809032103 |
Sumario: | The asymmetric unit of the title compound, [Zn(C(12)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2), contains one-half of the complex molecule and one NO(3) (−) anion. The Zn(II) ion displays a distorted tetragonal-pyramidal geometry with four N atoms from two chelating 4-amino-3,5-di-2-pyridyl-1,2,4-triazole (2-bpt) ligands in the basal plane and one water molecule occupying the apical site. Another water molecule at the opposite of the apical site has a weak interaction with the Zn(II) ion [Zn—O = 2.852 (5) Å]. The Zn(II) ion and the two water molecules lie on a twofold rotation axis. An extensive system of hydrogen bonds involving the NH(2) groups of the 2-bpt ligands, water molecules and nitrate anions links all residues into a three-dimensional network. |
---|