2-(4-Methyl­anilino)acetohydrazide

In the title mol­ecule, C(9)H(13)N(3)O, the non-hydrogen atoms of the hydrazide group are essentially planar [maximum deviation = 0.028 (1) Å for one of the N atoms]. The mean plane of this group forms a dihedral angle of 83.34 (5)° with the plane of the benzene ring. In the crystal structure, mol­e...

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Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Malladi, Shridhar, Padaki, Mahesh, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969944/
https://www.ncbi.nlm.nih.gov/pubmed/21577633
http://dx.doi.org/10.1107/S1600536809033169
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author Fun, Hoong-Kun
Yeap, Chin Sing
Malladi, Shridhar
Padaki, Mahesh
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Malladi, Shridhar
Padaki, Mahesh
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecule, C(9)H(13)N(3)O, the non-hydrogen atoms of the hydrazide group are essentially planar [maximum deviation = 0.028 (1) Å for one of the N atoms]. The mean plane of this group forms a dihedral angle of 83.34 (5)° with the plane of the benzene ring. In the crystal structure, mol­ecules are linked by inter­molecular N—H⋯O, N—H⋯N and weak C—H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane. Additional stabilization is provided by a weak C—H⋯π inter­action.
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spelling pubmed-29699442010-12-30 2-(4-Methyl­anilino)acetohydrazide Fun, Hoong-Kun Yeap, Chin Sing Malladi, Shridhar Padaki, Mahesh Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(9)H(13)N(3)O, the non-hydrogen atoms of the hydrazide group are essentially planar [maximum deviation = 0.028 (1) Å for one of the N atoms]. The mean plane of this group forms a dihedral angle of 83.34 (5)° with the plane of the benzene ring. In the crystal structure, mol­ecules are linked by inter­molecular N—H⋯O, N—H⋯N and weak C—H⋯N hydrogen bonds into a two-dimensional network parallel to the ab plane. Additional stabilization is provided by a weak C—H⋯π inter­action. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969944/ /pubmed/21577633 http://dx.doi.org/10.1107/S1600536809033169 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Malladi, Shridhar
Padaki, Mahesh
Isloor, Arun M.
2-(4-Methyl­anilino)acetohydrazide
title 2-(4-Methyl­anilino)acetohydrazide
title_full 2-(4-Methyl­anilino)acetohydrazide
title_fullStr 2-(4-Methyl­anilino)acetohydrazide
title_full_unstemmed 2-(4-Methyl­anilino)acetohydrazide
title_short 2-(4-Methyl­anilino)acetohydrazide
title_sort 2-(4-methyl­anilino)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969944/
https://www.ncbi.nlm.nih.gov/pubmed/21577633
http://dx.doi.org/10.1107/S1600536809033169
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AT malladishridhar 24methylanilinoacetohydrazide
AT padakimahesh 24methylanilinoacetohydrazide
AT isloorarunm 24methylanilinoacetohydrazide

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