Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)

The Zn(II) ion in the title complex, [Zn(NCS)(2)(C(7)H(6)N(2)S)(2)], is tetra­hedrally coordinated within an N(4) donor set defined by two N atoms of two terminal isothio­cyanate ligands and by two heterocyclic N atoms of two different 2-amino­benzothia­zole ligands. This arrangement is stabilized b...

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Detalles Bibliográficos
Autores principales: Suh, Seung Wook, Kim, Chong-Hyeak, Kim, Inn Hoe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969946/
https://www.ncbi.nlm.nih.gov/pubmed/21577414
http://dx.doi.org/10.1107/S1600536809030931
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author Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
author_facet Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
author_sort Suh, Seung Wook
collection PubMed
description The Zn(II) ion in the title complex, [Zn(NCS)(2)(C(7)H(6)N(2)S)(2)], is tetra­hedrally coordinated within an N(4) donor set defined by two N atoms of two terminal isothio­cyanate ligands and by two heterocyclic N atoms of two different 2-amino­benzothia­zole ligands. This arrangement is stabilized by intra­molecular N—H⋯N hydrogen bonds. In the crystal structure, mol­ecules are linked through N—H⋯S hydrogen bonds to form a two-dimensional array.
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spelling pubmed-29699462010-12-30 Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II) Suh, Seung Wook Kim, Chong-Hyeak Kim, Inn Hoe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) ion in the title complex, [Zn(NCS)(2)(C(7)H(6)N(2)S)(2)], is tetra­hedrally coordinated within an N(4) donor set defined by two N atoms of two terminal isothio­cyanate ligands and by two heterocyclic N atoms of two different 2-amino­benzothia­zole ligands. This arrangement is stabilized by intra­molecular N—H⋯N hydrogen bonds. In the crystal structure, mol­ecules are linked through N—H⋯S hydrogen bonds to form a two-dimensional array. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969946/ /pubmed/21577414 http://dx.doi.org/10.1107/S1600536809030931 Text en © Suh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title_full Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title_fullStr Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title_full_unstemmed Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title_short Bis(2-amino­benzothia­zole-κN (1))bis­(thio­cyanato-κN)zinc(II)
title_sort bis(2-amino­benzothia­zole-κn (1))bis­(thio­cyanato-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969946/
https://www.ncbi.nlm.nih.gov/pubmed/21577414
http://dx.doi.org/10.1107/S1600536809030931
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AT kimchonghyeak bis2aminobenzothiazolekn1bisthiocyanatoknzincii
AT kiminnhoe bis2aminobenzothiazolekn1bisthiocyanatoknzincii

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