catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]

The title compound, [Zn(C(8)H(6)O(3))(2)(C(12)H(12)N(2))](n), consists of [Zn(Hopa)(2)] (H(2)opa = 2-hydr­oxy-2-phenyl­acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged...

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Detalles Bibliográficos
Autores principales: Yu, Seung Man, Shin, Dong Hoon, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969950/
https://www.ncbi.nlm.nih.gov/pubmed/21577407
http://dx.doi.org/10.1107/S1600536809030281
Descripción
Sumario:The title compound, [Zn(C(8)H(6)O(3))(2)(C(12)H(12)N(2))](n), consists of [Zn(Hopa)(2)] (H(2)opa = 2-hydr­oxy-2-phenyl­acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C—C bond. The geometry around the Zn(II) ion is distorted octa­hedral, constructed by four O atoms from two Hopa(−) ligands and two N atoms from two bridging bpe ligands. O—H⋯O hydrogen bonds link the chains, forming a three-dimensional network.

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