catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]

The title compound, [Zn(C(8)H(6)O(3))(2)(C(12)H(12)N(2))](n), consists of [Zn(Hopa)(2)] (H(2)opa = 2-hydr­oxy-2-phenyl­acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged...

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Detalles Bibliográficos
Autores principales: Yu, Seung Man, Shin, Dong Hoon, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969950/
https://www.ncbi.nlm.nih.gov/pubmed/21577407
http://dx.doi.org/10.1107/S1600536809030281
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author Yu, Seung Man
Shin, Dong Hoon
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Yu, Seung Man
Shin, Dong Hoon
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Yu, Seung Man
collection PubMed
description The title compound, [Zn(C(8)H(6)O(3))(2)(C(12)H(12)N(2))](n), consists of [Zn(Hopa)(2)] (H(2)opa = 2-hydr­oxy-2-phenyl­acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C—C bond. The geometry around the Zn(II) ion is distorted octa­hedral, constructed by four O atoms from two Hopa(−) ligands and two N atoms from two bridging bpe ligands. O—H⋯O hydrogen bonds link the chains, forming a three-dimensional network.
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spelling pubmed-29699502010-12-30 catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′] Yu, Seung Man Shin, Dong Hoon Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(6)O(3))(2)(C(12)H(12)N(2))](n), consists of [Zn(Hopa)(2)] (H(2)opa = 2-hydr­oxy-2-phenyl­acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C—C bond. The geometry around the Zn(II) ion is distorted octa­hedral, constructed by four O atoms from two Hopa(−) ligands and two N atoms from two bridging bpe ligands. O—H⋯O hydrogen bonds link the chains, forming a three-dimensional network. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969950/ /pubmed/21577407 http://dx.doi.org/10.1107/S1600536809030281 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Seung Man
Shin, Dong Hoon
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title_full catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title_fullStr catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title_full_unstemmed catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title_short catena-Poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) O (1),O (2))zinc(II)]-μ-1,2-di-4-pyridylethane-κ(2) N:N′]
title_sort catena-poly[[bis­(2-hydr­oxy-2-phenyl­acetato-κ(2) o (1),o (2))zinc(ii)]-μ-1,2-di-4-pyridylethane-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969950/
https://www.ncbi.nlm.nih.gov/pubmed/21577407
http://dx.doi.org/10.1107/S1600536809030281
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