catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]

In the title compound, {[Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·2H(2)O}(n), the Cd(II) atom is seven-coordinated by two N atoms from the phenanthroline-derived 4,5-diaza­fluorene-9-one ligand, two O atoms from one bidentate benzene-1,3-dicarboxyl­ate ligand and three O atoms from the three wate...

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Detalles Bibliográficos
Autores principales: Li, Xiao-Ping, Fang, Wei, Mei, Ze-Min, Jin, Xiang-Jun, Qi, Wen-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969955/
https://www.ncbi.nlm.nih.gov/pubmed/21577425
http://dx.doi.org/10.1107/S1600536809031237
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author Li, Xiao-Ping
Fang, Wei
Mei, Ze-Min
Jin, Xiang-Jun
Qi, Wen-Liang
author_facet Li, Xiao-Ping
Fang, Wei
Mei, Ze-Min
Jin, Xiang-Jun
Qi, Wen-Liang
author_sort Li, Xiao-Ping
collection PubMed
description In the title compound, {[Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·2H(2)O}(n), the Cd(II) atom is seven-coordinated by two N atoms from the phenanthroline-derived 4,5-diaza­fluorene-9-one ligand, two O atoms from one bidentate benzene-1,3-dicarboxyl­ate ligand and three O atoms from the three water mol­ecules in a distorted penta­gonal-bipyramidal arrangement. Moreover, there are two dissociative water mol­ecules in each unit. Neighbouring units inter­act through π–π inter­actions [centroid–centroid distances = 3.325 (3) and 3.358 (4) Å] and O—H⋯O hydrogen-bonding, resulting in a two-dimensional network extending parallel to (001).
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spelling pubmed-29699552010-12-30 catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate] Li, Xiao-Ping Fang, Wei Mei, Ze-Min Jin, Xiang-Jun Qi, Wen-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·2H(2)O}(n), the Cd(II) atom is seven-coordinated by two N atoms from the phenanthroline-derived 4,5-diaza­fluorene-9-one ligand, two O atoms from one bidentate benzene-1,3-dicarboxyl­ate ligand and three O atoms from the three water mol­ecules in a distorted penta­gonal-bipyramidal arrangement. Moreover, there are two dissociative water mol­ecules in each unit. Neighbouring units inter­act through π–π inter­actions [centroid–centroid distances = 3.325 (3) and 3.358 (4) Å] and O—H⋯O hydrogen-bonding, resulting in a two-dimensional network extending parallel to (001). International Union of Crystallography 2009-08-15 /pmc/articles/PMC2969955/ /pubmed/21577425 http://dx.doi.org/10.1107/S1600536809031237 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiao-Ping
Fang, Wei
Mei, Ze-Min
Jin, Xiang-Jun
Qi, Wen-Liang
catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title_full catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title_fullStr catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title_full_unstemmed catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title_short catena-Poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
title_sort catena-poly[[[triaqua­(4,5-diaza­fluorene-9-one)cadmium]-μ-benzene-1,3-dicarboxyl­ato] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969955/
https://www.ncbi.nlm.nih.gov/pubmed/21577425
http://dx.doi.org/10.1107/S1600536809031237
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