(E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate

In the title compound, C(14)H(9)Br(2)N(3)O(4)·CH(3)OH, the Schiff base mol­ecule adopts an E geometry with respect to the C=N bond and the benzene rings are oriented at a dihedral angle of 45.3 (2)°. An intra­molecular O—H⋯N hydrogen bond helps to establish the conformation. In the crystal, the meth...

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Detalles Bibliográficos
Autores principales: Qian, Heng-Yu, Qu, Da-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969957/
https://www.ncbi.nlm.nih.gov/pubmed/21577635
http://dx.doi.org/10.1107/S160053680903311X
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author Qian, Heng-Yu
Qu, Da-Ping
author_facet Qian, Heng-Yu
Qu, Da-Ping
author_sort Qian, Heng-Yu
collection PubMed
description In the title compound, C(14)H(9)Br(2)N(3)O(4)·CH(3)OH, the Schiff base mol­ecule adopts an E geometry with respect to the C=N bond and the benzene rings are oriented at a dihedral angle of 45.3 (2)°. An intra­molecular O—H⋯N hydrogen bond helps to establish the conformation. In the crystal, the methanol solvent mol­ecule is linked to the Schiff base mol­ecule through an O—H⋯O hydrogen bond and inter­molecular N—H⋯O hydrogen bonds link the components to form layers parallel to the bc direction.
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spelling pubmed-29699572010-12-30 (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate Qian, Heng-Yu Qu, Da-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(9)Br(2)N(3)O(4)·CH(3)OH, the Schiff base mol­ecule adopts an E geometry with respect to the C=N bond and the benzene rings are oriented at a dihedral angle of 45.3 (2)°. An intra­molecular O—H⋯N hydrogen bond helps to establish the conformation. In the crystal, the methanol solvent mol­ecule is linked to the Schiff base mol­ecule through an O—H⋯O hydrogen bond and inter­molecular N—H⋯O hydrogen bonds link the components to form layers parallel to the bc direction. International Union of Crystallography 2009-08-26 /pmc/articles/PMC2969957/ /pubmed/21577635 http://dx.doi.org/10.1107/S160053680903311X Text en © Qian and Qu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qian, Heng-Yu
Qu, Da-Ping
(E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title_full (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title_fullStr (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title_full_unstemmed (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title_short (E)-N′-(3,5-Dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
title_sort (e)-n′-(3,5-dibromo-2-hydroxy­benzyl­idene)-2-nitro­benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969957/
https://www.ncbi.nlm.nih.gov/pubmed/21577635
http://dx.doi.org/10.1107/S160053680903311X
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