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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate)
In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a square-planar geometry,...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969959/ https://www.ncbi.nlm.nih.gov/pubmed/21577390 http://dx.doi.org/10.1107/S1600536809030037 |
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author | Feng, Jian-Shen Zou, Li-Ke Xie, Bin Wu, Yu |
author_facet | Feng, Jian-Shen Zou, Li-Ke Xie, Bin Wu, Yu |
author_sort | Feng, Jian-Shen |
collection | PubMed |
description | In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a square-planar geometry, with Cu—N distances of 2.013 (3) and 2.014 (3) Å. In the crystal structure, one O,S-dibenzyl dithiophosphate counter-anion links with the Cu(II) complex cation through N—H⋯O and N—H⋯S hydrogen bonding. During the synthesis, the structure of the anion re-arranged from O,O′-dibenzyl dithiophosphate in the starting material to O,S-dibenzyl dithiophosphate in the title compound. |
format | Text |
id | pubmed-2969959 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29699592010-12-30 (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) Feng, Jian-Shen Zou, Li-Ke Xie, Bin Wu, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a square-planar geometry, with Cu—N distances of 2.013 (3) and 2.014 (3) Å. In the crystal structure, one O,S-dibenzyl dithiophosphate counter-anion links with the Cu(II) complex cation through N—H⋯O and N—H⋯S hydrogen bonding. During the synthesis, the structure of the anion re-arranged from O,O′-dibenzyl dithiophosphate in the starting material to O,S-dibenzyl dithiophosphate in the title compound. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969959/ /pubmed/21577390 http://dx.doi.org/10.1107/S1600536809030037 Text en © Feng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Feng, Jian-Shen Zou, Li-Ke Xie, Bin Wu, Yu (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title_full | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title_fullStr | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title_full_unstemmed | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title_short | (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis(O,S-dibenzyl dithiophosphate) |
title_sort | (meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(ii) bis(o,s-dibenzyl dithiophosphate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969959/ https://www.ncbi.nlm.nih.gov/pubmed/21577390 http://dx.doi.org/10.1107/S1600536809030037 |
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