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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)

In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ligand in a square-planar geometry,...

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Detalles Bibliográficos
Autores principales: Feng, Jian-Shen, Zou, Li-Ke, Xie, Bin, Wu, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969959/
https://www.ncbi.nlm.nih.gov/pubmed/21577390
http://dx.doi.org/10.1107/S1600536809030037
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author Feng, Jian-Shen
Zou, Li-Ke
Xie, Bin
Wu, Yu
author_facet Feng, Jian-Shen
Zou, Li-Ke
Xie, Bin
Wu, Yu
author_sort Feng, Jian-Shen
collection PubMed
description In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ligand in a square-planar geometry, with Cu—N distances of 2.013 (3) and 2.014 (3) Å. In the crystal structure, one O,S-dibenzyl dithio­phosphate counter-anion links with the Cu(II) complex cation through N—H⋯O and N—H⋯S hydrogen bonding. During the synthesis, the structure of the anion re-arranged from O,O′-dibenzyl dithio­phosphate in the starting material to O,S-dibenzyl dithio­phosphate in the title compound.
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spelling pubmed-29699592010-12-30 (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate) Feng, Jian-Shen Zou, Li-Ke Xie, Bin Wu, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(16)H(36)N(4))](C(14)H(14)O(2)PS(2))(2), the Cu(II) atom is located on an inversion center and is chelated by four N atoms of the macrocyclic meso-5,5,7,12,12,14- hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ligand in a square-planar geometry, with Cu—N distances of 2.013 (3) and 2.014 (3) Å. In the crystal structure, one O,S-dibenzyl dithio­phosphate counter-anion links with the Cu(II) complex cation through N—H⋯O and N—H⋯S hydrogen bonding. During the synthesis, the structure of the anion re-arranged from O,O′-dibenzyl dithio­phosphate in the starting material to O,S-dibenzyl dithio­phosphate in the title compound. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969959/ /pubmed/21577390 http://dx.doi.org/10.1107/S1600536809030037 Text en © Feng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Jian-Shen
Zou, Li-Ke
Xie, Bin
Wu, Yu
(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title_full (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title_fullStr (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title_full_unstemmed (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title_short (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(II) bis­(O,S-dibenzyl dithio­phosphate)
title_sort (meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetra­azacyclo­tetra­deca­ne)copper(ii) bis­(o,s-dibenzyl dithio­phosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969959/
https://www.ncbi.nlm.nih.gov/pubmed/21577390
http://dx.doi.org/10.1107/S1600536809030037
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