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N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide

In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent mol­ecules in the asymmetric unit, in which the heterocyclic thia­zine rings in both mol­ecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both mol­ecules are al...

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Autores principales: Siddiqui, Waseeq Ahmad, Siddiqui, Hamid Latif, Azam, Muhammad, Parvez, Masood, Rizvi, Umar Farooq
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969961/
https://www.ncbi.nlm.nih.gov/pubmed/21577673
http://dx.doi.org/10.1107/S1600536809033972
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author Siddiqui, Waseeq Ahmad
Siddiqui, Hamid Latif
Azam, Muhammad
Parvez, Masood
Rizvi, Umar Farooq
author_facet Siddiqui, Waseeq Ahmad
Siddiqui, Hamid Latif
Azam, Muhammad
Parvez, Masood
Rizvi, Umar Farooq
author_sort Siddiqui, Waseeq Ahmad
collection PubMed
description In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent mol­ecules in the asymmetric unit, in which the heterocyclic thia­zine rings in both mol­ecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both mol­ecules are all EZ. There are strong intra­molecular O—H⋯O and N—H⋯N hydrogen bonds resulting in graph-set patterns S(6) and S(5) for the oxo and amino rings, in addition to intra­molecular N—H⋯Cl inter­actions. In the crystal structure, mol­ecules are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds into chains along [100].
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spelling pubmed-29699612010-12-30 N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide Siddiqui, Waseeq Ahmad Siddiqui, Hamid Latif Azam, Muhammad Parvez, Masood Rizvi, Umar Farooq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent mol­ecules in the asymmetric unit, in which the heterocyclic thia­zine rings in both mol­ecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both mol­ecules are all EZ. There are strong intra­molecular O—H⋯O and N—H⋯N hydrogen bonds resulting in graph-set patterns S(6) and S(5) for the oxo and amino rings, in addition to intra­molecular N—H⋯Cl inter­actions. In the crystal structure, mol­ecules are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds into chains along [100]. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2969961/ /pubmed/21577673 http://dx.doi.org/10.1107/S1600536809033972 Text en © Siddiqui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siddiqui, Waseeq Ahmad
Siddiqui, Hamid Latif
Azam, Muhammad
Parvez, Masood
Rizvi, Umar Farooq
N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title_full N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title_fullStr N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title_full_unstemmed N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title_short N-(2-Chloro­phen­yl)-4-hydr­oxy-2H-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
title_sort n-(2-chloro­phen­yl)-4-hydr­oxy-2h-1,2-benzothia­zine-3-carboxamide 1,1-dioxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969961/
https://www.ncbi.nlm.nih.gov/pubmed/21577673
http://dx.doi.org/10.1107/S1600536809033972
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