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N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide
In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent molecules in the asymmetric unit, in which the heterocyclic thiazine rings in both molecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both molecules are al...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969961/ https://www.ncbi.nlm.nih.gov/pubmed/21577673 http://dx.doi.org/10.1107/S1600536809033972 |
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author | Siddiqui, Waseeq Ahmad Siddiqui, Hamid Latif Azam, Muhammad Parvez, Masood Rizvi, Umar Farooq |
author_facet | Siddiqui, Waseeq Ahmad Siddiqui, Hamid Latif Azam, Muhammad Parvez, Masood Rizvi, Umar Farooq |
author_sort | Siddiqui, Waseeq Ahmad |
collection | PubMed |
description | In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent molecules in the asymmetric unit, in which the heterocyclic thiazine rings in both molecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both molecules are all EZ. There are strong intramolecular O—H⋯O and N—H⋯N hydrogen bonds resulting in graph-set patterns S(6) and S(5) for the oxo and amino rings, in addition to intramolecular N—H⋯Cl interactions. In the crystal structure, molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds into chains along [100]. |
format | Text |
id | pubmed-2969961 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29699612010-12-30 N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide Siddiqui, Waseeq Ahmad Siddiqui, Hamid Latif Azam, Muhammad Parvez, Masood Rizvi, Umar Farooq Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(11)ClN(2)O(4)S, there are two independent molecules in the asymmetric unit, in which the heterocyclic thiazine rings in both molecules adopt half-chair conformations. The conformations about the C—C and C—N bonds in the central C—C—N—C chain in both molecules are all EZ. There are strong intramolecular O—H⋯O and N—H⋯N hydrogen bonds resulting in graph-set patterns S(6) and S(5) for the oxo and amino rings, in addition to intramolecular N—H⋯Cl interactions. In the crystal structure, molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds into chains along [100]. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2969961/ /pubmed/21577673 http://dx.doi.org/10.1107/S1600536809033972 Text en © Siddiqui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Siddiqui, Waseeq Ahmad Siddiqui, Hamid Latif Azam, Muhammad Parvez, Masood Rizvi, Umar Farooq N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title |
N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title_full |
N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title_fullStr |
N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title_full_unstemmed |
N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title_short |
N-(2-Chlorophenyl)-4-hydroxy-2H-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
title_sort | n-(2-chlorophenyl)-4-hydroxy-2h-1,2-benzothiazine-3-carboxamide 1,1-dioxide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969961/ https://www.ncbi.nlm.nih.gov/pubmed/21577673 http://dx.doi.org/10.1107/S1600536809033972 |
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