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Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III)
The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxysalicylaldehyde in presence of manganese(II) 4-hydroxybenzoate. The Jahn–Teller-distorted manganese(III) centre has an octahedral geometry. Extensive O—H⋯O...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969974/ https://www.ncbi.nlm.nih.gov/pubmed/21577455 http://dx.doi.org/10.1107/S1600536809032553 |
| _version_ | 1782190311722713088 |
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| author | Reshma, R. Soumya, P. V. Simi, S. M. Thampidas, V. S. Pike, Robert D. |
| author_facet | Reshma, R. Soumya, P. V. Simi, S. M. Thampidas, V. S. Pike, Robert D. |
| author_sort | Reshma, R. |
| collection | PubMed |
| description | The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxysalicylaldehyde in presence of manganese(II) 4-hydroxybenzoate. The Jahn–Teller-distorted manganese(III) centre has an octahedral geometry. Extensive O—H⋯O hydrogen-bonding interactions generate a two-dimensional sheet structure parallel to (103). |
| format | Text |
| id | pubmed-2969974 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29699742010-12-30 Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) Reshma, R. Soumya, P. V. Simi, S. M. Thampidas, V. S. Pike, Robert D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxysalicylaldehyde in presence of manganese(II) 4-hydroxybenzoate. The Jahn–Teller-distorted manganese(III) centre has an octahedral geometry. Extensive O—H⋯O hydrogen-bonding interactions generate a two-dimensional sheet structure parallel to (103). International Union of Crystallography 2009-08-22 /pmc/articles/PMC2969974/ /pubmed/21577455 http://dx.doi.org/10.1107/S1600536809032553 Text en © Reshma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Reshma, R. Soumya, P. V. Simi, S. M. Thampidas, V. S. Pike, Robert D. Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title_full | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title_fullStr | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title_full_unstemmed | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title_short | Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(III) |
| title_sort | aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}(4-hydroxybenzoato)manganese(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969974/ https://www.ncbi.nlm.nih.gov/pubmed/21577455 http://dx.doi.org/10.1107/S1600536809032553 |
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