Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate

The Co ion in the title salt, [Co(NO(3))(H(2)NCH(2)CH(2)NH(2))(2)](OH)(NO(3)), has oxidation state + III and is coordinated by four N atoms from two ethyl­enediamine mol­ecules and two O atoms from a nitrate anion in a distorted octa­hedral geometry. The charge of the complex cation is balanced by a...

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Detalles Bibliográficos
Autores principales: Zhang, Ji-Bo, Qu, Xiao-Shu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969983/
https://www.ncbi.nlm.nih.gov/pubmed/21577449
http://dx.doi.org/10.1107/S160053680903219X
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author Zhang, Ji-Bo
Qu, Xiao-Shu
author_facet Zhang, Ji-Bo
Qu, Xiao-Shu
author_sort Zhang, Ji-Bo
collection PubMed
description The Co ion in the title salt, [Co(NO(3))(H(2)NCH(2)CH(2)NH(2))(2)](OH)(NO(3)), has oxidation state + III and is coordinated by four N atoms from two ethyl­enediamine mol­ecules and two O atoms from a nitrate anion in a distorted octa­hedral geometry. The charge of the complex cation is balanced by a hydroxide anion and a nitrate anion. The cations and anions are connected by N—H⋯O and O—H⋯O hydrogen bonds, resulting in a three-dimensional supra­molecular framework. There are two independent ion pairs with similar configurations in the unit cell. Both uncoordinated nitrate counter-anions are disordered.
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spelling pubmed-29699832010-12-30 Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate Zhang, Ji-Bo Qu, Xiao-Shu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co ion in the title salt, [Co(NO(3))(H(2)NCH(2)CH(2)NH(2))(2)](OH)(NO(3)), has oxidation state + III and is coordinated by four N atoms from two ethyl­enediamine mol­ecules and two O atoms from a nitrate anion in a distorted octa­hedral geometry. The charge of the complex cation is balanced by a hydroxide anion and a nitrate anion. The cations and anions are connected by N—H⋯O and O—H⋯O hydrogen bonds, resulting in a three-dimensional supra­molecular framework. There are two independent ion pairs with similar configurations in the unit cell. Both uncoordinated nitrate counter-anions are disordered. International Union of Crystallography 2009-08-19 /pmc/articles/PMC2969983/ /pubmed/21577449 http://dx.doi.org/10.1107/S160053680903219X Text en © Zhang and Qu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ji-Bo
Qu, Xiao-Shu
Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title_full Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title_fullStr Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title_full_unstemmed Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title_short Bis(ethyl­enediamine-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(III) hydroxide nitrate
title_sort bis(ethyl­enediamine-κ(2) n,n′)(nitrato-κ(2) o,o′)cobalt(iii) hydroxide nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969983/
https://www.ncbi.nlm.nih.gov/pubmed/21577449
http://dx.doi.org/10.1107/S160053680903219X
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