(Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)

In the title complex, [V(C(9)H(6)NO)(2)(CH(3)O)O], the central V(V) atom is coordinated by the O atoms from the oxido and methoxo ligands and the N and O atoms of two bis-chelating quinolin-8-olate ligands, forming a distorted octa­hedral environment. In the crystal structure, weak inter­molecular C...

Descripción completa

Detalles Bibliográficos
Autores principales: Guo, Zhenghua, Li, Lianzhi, Wang, Chengyuan, Xu, Tao, Li, Jinghong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969990/
https://www.ncbi.nlm.nih.gov/pubmed/21577429
http://dx.doi.org/10.1107/S1600536809031560
_version_ 1782190316068012032
author Guo, Zhenghua
Li, Lianzhi
Wang, Chengyuan
Xu, Tao
Li, Jinghong
author_facet Guo, Zhenghua
Li, Lianzhi
Wang, Chengyuan
Xu, Tao
Li, Jinghong
author_sort Guo, Zhenghua
collection PubMed
description In the title complex, [V(C(9)H(6)NO)(2)(CH(3)O)O], the central V(V) atom is coordinated by the O atoms from the oxido and methoxo ligands and the N and O atoms of two bis-chelating quinolin-8-olate ligands, forming a distorted octa­hedral environment. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect mol­ecules into centrosymmetric dimers which are, in turn, linked by weak C—H⋯π inter­actions into chains along the b axis.
format Text
id pubmed-2969990
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29699902010-12-30 (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V) Guo, Zhenghua Li, Lianzhi Wang, Chengyuan Xu, Tao Li, Jinghong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [V(C(9)H(6)NO)(2)(CH(3)O)O], the central V(V) atom is coordinated by the O atoms from the oxido and methoxo ligands and the N and O atoms of two bis-chelating quinolin-8-olate ligands, forming a distorted octa­hedral environment. In the crystal structure, weak inter­molecular C—H⋯O hydrogen bonds connect mol­ecules into centrosymmetric dimers which are, in turn, linked by weak C—H⋯π inter­actions into chains along the b axis. International Union of Crystallography 2009-08-15 /pmc/articles/PMC2969990/ /pubmed/21577429 http://dx.doi.org/10.1107/S1600536809031560 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Zhenghua
Li, Lianzhi
Wang, Chengyuan
Xu, Tao
Li, Jinghong
(Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title_full (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title_fullStr (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title_full_unstemmed (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title_short (Methoxo-κO)oxidobis(quinolin-8-olato-κ(2) N,O)vanadium(V)
title_sort (methoxo-κo)oxidobis(quinolin-8-olato-κ(2) n,o)vanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969990/
https://www.ncbi.nlm.nih.gov/pubmed/21577429
http://dx.doi.org/10.1107/S1600536809031560
work_keys_str_mv AT guozhenghua methoxokooxidobisquinolin8olatok2novanadiumv
AT lilianzhi methoxokooxidobisquinolin8olatok2novanadiumv
AT wangchengyuan methoxokooxidobisquinolin8olatok2novanadiumv
AT xutao methoxokooxidobisquinolin8olatok2novanadiumv
AT lijinghong methoxokooxidobisquinolin8olatok2novanadiumv

Ejemplares similares