Cargando…

{1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate

In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate 1,1′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphtholate Schiff base ligand in a...

Descripción completa

Detalles Bibliográficos
Autores principales: Monadi, Niaz, Sheikhshoaie, Iran, Rezaeifard, Abdoreza, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969995/
https://www.ncbi.nlm.nih.gov/pubmed/21577465
http://dx.doi.org/10.1107/S1600536809032759
_version_ 1782190317300088832
author Monadi, Niaz
Sheikhshoaie, Iran
Rezaeifard, Abdoreza
Stoeckli-Evans, Helen
author_facet Monadi, Niaz
Sheikhshoaie, Iran
Rezaeifard, Abdoreza
Stoeckli-Evans, Helen
author_sort Monadi, Niaz
collection PubMed
description In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate 1,1′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphtholate Schiff base ligand in a distorted octa­hedral configuration. The compound crystallizes with 1.75 mol­ecules of dichloro­methane per complex mol­ecule. In the crystal, symmetry-related mol­ecules are linked by a number of C—H⋯O inter­actions involving both the Schiff base ligand and the partly disordered dichloro­methane solvent mol­ecules, leading to the formation of a two-dimensional network extending parallel to (101).
format Text
id pubmed-2969995
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29699952010-12-30 {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate Monadi, Niaz Sheikhshoaie, Iran Rezaeifard, Abdoreza Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate 1,1′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphtholate Schiff base ligand in a distorted octa­hedral configuration. The compound crystallizes with 1.75 mol­ecules of dichloro­methane per complex mol­ecule. In the crystal, symmetry-related mol­ecules are linked by a number of C—H⋯O inter­actions involving both the Schiff base ligand and the partly disordered dichloro­methane solvent mol­ecules, leading to the formation of a two-dimensional network extending parallel to (101). International Union of Crystallography 2009-08-22 /pmc/articles/PMC2969995/ /pubmed/21577465 http://dx.doi.org/10.1107/S1600536809032759 Text en © Monadi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Monadi, Niaz
Sheikhshoaie, Iran
Rezaeifard, Abdoreza
Stoeckli-Evans, Helen
{1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title_full {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title_fullStr {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title_full_unstemmed {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title_short {1,1′-[(2,2-Dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(VI) dichloro­methane 1.75-solvate
title_sort {1,1′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methyl­idyne)]di-2-naphthol­ato}dioxidomolybdenum(vi) dichloro­methane 1.75-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969995/
https://www.ncbi.nlm.nih.gov/pubmed/21577465
http://dx.doi.org/10.1107/S1600536809032759
work_keys_str_mv AT monadiniaz 1122dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT sheikhshoaieiran 1122dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT rezaeifardabdoreza 1122dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate
AT stoecklievanshelen 1122dimethylpropane13diylbisnitrilomethylidynedi2naphtholatodioxidomolybdenumvidichloromethane175solvate