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{1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate
In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969995/ https://www.ncbi.nlm.nih.gov/pubmed/21577465 http://dx.doi.org/10.1107/S1600536809032759 |
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author | Monadi, Niaz Sheikhshoaie, Iran Rezaeifard, Abdoreza Stoeckli-Evans, Helen |
author_facet | Monadi, Niaz Sheikhshoaie, Iran Rezaeifard, Abdoreza Stoeckli-Evans, Helen |
author_sort | Monadi, Niaz |
collection | PubMed |
description | In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a distorted octahedral configuration. The compound crystallizes with 1.75 molecules of dichloromethane per complex molecule. In the crystal, symmetry-related molecules are linked by a number of C—H⋯O interactions involving both the Schiff base ligand and the partly disordered dichloromethane solvent molecules, leading to the formation of a two-dimensional network extending parallel to (101). |
format | Text |
id | pubmed-2969995 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29699952010-12-30 {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate Monadi, Niaz Sheikhshoaie, Iran Rezaeifard, Abdoreza Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a distorted octahedral configuration. The compound crystallizes with 1.75 molecules of dichloromethane per complex molecule. In the crystal, symmetry-related molecules are linked by a number of C—H⋯O interactions involving both the Schiff base ligand and the partly disordered dichloromethane solvent molecules, leading to the formation of a two-dimensional network extending parallel to (101). International Union of Crystallography 2009-08-22 /pmc/articles/PMC2969995/ /pubmed/21577465 http://dx.doi.org/10.1107/S1600536809032759 Text en © Monadi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Monadi, Niaz Sheikhshoaie, Iran Rezaeifard, Abdoreza Stoeckli-Evans, Helen {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title | {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title_full | {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title_fullStr | {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title_full_unstemmed | {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title_short | {1,1′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(VI) dichloromethane 1.75-solvate |
title_sort | {1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholato}dioxidomolybdenum(vi) dichloromethane 1.75-solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969995/ https://www.ncbi.nlm.nih.gov/pubmed/21577465 http://dx.doi.org/10.1107/S1600536809032759 |
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