Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]

In the title compound, {[Co(C(8)H(4)O(4))(C(10)H(8)N(4))]·2C(3)H(7)NO·0.5H(2)O}(n), the Co(II) atom is six-coordinated by four O atoms from two benzene-1,4-dicarboxyl­ate (H(2)bdc(2−)) groups and two N atoms from two 4,4′-azopyridine (4,4′-azpy, or di-4-pyridyldiazene) ligands, leading to a distorte...

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Detalles Bibliográficos
Autores principales: Chu, Chao-Xia, Zhang, Ying, Zhou, Hu, Yuan, Ai-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969999/
https://www.ncbi.nlm.nih.gov/pubmed/21577400
http://dx.doi.org/10.1107/S1600536809030189
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author Chu, Chao-Xia
Zhang, Ying
Zhou, Hu
Yuan, Ai-Hua
author_facet Chu, Chao-Xia
Zhang, Ying
Zhou, Hu
Yuan, Ai-Hua
author_sort Chu, Chao-Xia
collection PubMed
description In the title compound, {[Co(C(8)H(4)O(4))(C(10)H(8)N(4))]·2C(3)H(7)NO·0.5H(2)O}(n), the Co(II) atom is six-coordinated by four O atoms from two benzene-1,4-dicarboxyl­ate (H(2)bdc(2−)) groups and two N atoms from two 4,4′-azopyridine (4,4′-azpy, or di-4-pyridyldiazene) ligands, leading to a distorted octa­hedral geometry. The structure consists of two-dimensional corrugated sheets with a 4(4) topology in an …ABAB… packing pattern stacking along the a axis. The separation of the adjacent corrugated sheets is ca. 8.561 (2)  Å (Co⋯Co distance) along the a axis. The uncoordinated water molecule is half-occupied. The crystal structure is stabilized by O—H⋯N and C—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29699992010-12-30 Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate] Chu, Chao-Xia Zhang, Ying Zhou, Hu Yuan, Ai-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(8)H(4)O(4))(C(10)H(8)N(4))]·2C(3)H(7)NO·0.5H(2)O}(n), the Co(II) atom is six-coordinated by four O atoms from two benzene-1,4-dicarboxyl­ate (H(2)bdc(2−)) groups and two N atoms from two 4,4′-azopyridine (4,4′-azpy, or di-4-pyridyldiazene) ligands, leading to a distorted octa­hedral geometry. The structure consists of two-dimensional corrugated sheets with a 4(4) topology in an …ABAB… packing pattern stacking along the a axis. The separation of the adjacent corrugated sheets is ca. 8.561 (2)  Å (Co⋯Co distance) along the a axis. The uncoordinated water molecule is half-occupied. The crystal structure is stabilized by O—H⋯N and C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2969999/ /pubmed/21577400 http://dx.doi.org/10.1107/S1600536809030189 Text en © Chu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chu, Chao-Xia
Zhang, Ying
Zhou, Hu
Yuan, Ai-Hua
Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title_full Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title_fullStr Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title_full_unstemmed Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title_short Poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) O (1),O (1′):O (4),O (4′))(μ(2)-di-4-pyridyldiazene-κ(2) N (1):N (1′))cobalt(II)] N,N-dimethyl­formamide disolvate hemihydrate]
title_sort poly[[(μ(2)-benzene-1,4-dicarboxyl­ato-κ(4) o (1),o (1′):o (4),o (4′))(μ(2)-di-4-pyridyldiazene-κ(2) n (1):n (1′))cobalt(ii)] n,n-dimethyl­formamide disolvate hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969999/
https://www.ncbi.nlm.nih.gov/pubmed/21577400
http://dx.doi.org/10.1107/S1600536809030189
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