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(η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II)
The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclooctadiene ring, is similar to its Cl and Br orthorhombic homologues. The observed Pt—I bond distances of 2.6094 (5) and 2.6130 (5) Å are in the expected range for PtI(2) complexes. The C=C double bonds in the mol...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970000/ https://www.ncbi.nlm.nih.gov/pubmed/21577395 http://dx.doi.org/10.1107/S1600536809029997 |
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| author | Thibault, Marie-Hélène Fontaine, Frédéric-Georges |
| author_facet | Thibault, Marie-Hélène Fontaine, Frédéric-Georges |
| author_sort | Thibault, Marie-Hélène |
| collection | PubMed |
| description | The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclooctadiene ring, is similar to its Cl and Br orthorhombic homologues. The observed Pt—I bond distances of 2.6094 (5) and 2.6130 (5) Å are in the expected range for PtI(2) complexes. The C=C double bonds in the molecule differ significantly [1.373 (10) and 1.403 (10) Å]. As expected for a platinum(II) complex, the Pt(II) atom is in a square-planar environment (ΣPt(α)= 359.71°). |
| format | Text |
| id | pubmed-2970000 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29700002010-12-30 (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) Thibault, Marie-Hélène Fontaine, Frédéric-Georges Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The monoclinic title complex, [PtI(2)(C(8)H(12))], characterized by a twisted cyclooctadiene ring, is similar to its Cl and Br orthorhombic homologues. The observed Pt—I bond distances of 2.6094 (5) and 2.6130 (5) Å are in the expected range for PtI(2) complexes. The C=C double bonds in the molecule differ significantly [1.373 (10) and 1.403 (10) Å]. As expected for a platinum(II) complex, the Pt(II) atom is in a square-planar environment (ΣPt(α)= 359.71°). International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970000/ /pubmed/21577395 http://dx.doi.org/10.1107/S1600536809029997 Text en © Thibault and Fontaine 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Thibault, Marie-Hélène Fontaine, Frédéric-Georges (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title | (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title_full | (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title_fullStr | (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title_full_unstemmed | (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title_short | (η(4)-Cycloocta-1,5-diene)diiodidoplatinum(II) |
| title_sort | (η(4)-cycloocta-1,5-diene)diiodidoplatinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970000/ https://www.ncbi.nlm.nih.gov/pubmed/21577395 http://dx.doi.org/10.1107/S1600536809029997 |
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