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Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]

In the title compound, {[Nd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(H(2)O)(2)]·2.5H(2)O}(n), the Nd(II) ion is nine-coordinated by seven O atoms from five carboxyl­ate groups and two water mol­ecules. The [Nd(C(8)H(3)NO(6))(H(2)O)(2)](2+) units are bridged by 5-nitro­isophthalate dianions, forming polymeric s...

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Detalles Bibliográficos
Autores principales: Raime, Nurul-Nadia, Adnan, Rohana, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970002/
https://www.ncbi.nlm.nih.gov/pubmed/21577454
http://dx.doi.org/10.1107/S1600536809032486
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author Raime, Nurul-Nadia
Adnan, Rohana
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Raime, Nurul-Nadia
Adnan, Rohana
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Raime, Nurul-Nadia
collection PubMed
description In the title compound, {[Nd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(H(2)O)(2)]·2.5H(2)O}(n), the Nd(II) ion is nine-coordinated by seven O atoms from five carboxyl­ate groups and two water mol­ecules. The [Nd(C(8)H(3)NO(6))(H(2)O)(2)](2+) units are bridged by 5-nitro­isophthalate dianions, forming polymeric sheets parallel to the ab plane. The polymeric sheets are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds, and π–π inter­actions [centroid–centroid distance = 3.5533 (11) Å]. The 5-nitro­isophthalate(1−) anion is disordered over three positions with an occupancy ratio of 0.68:0.23:0.09. Two of the uncoordinated water mol­ecules are disordered over two positions, with occupancy ratios of 0.722 (15):0.278 (15) and 0.279 (6):0.221 (6), respectively.
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spelling pubmed-29700022010-12-30 Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate] Raime, Nurul-Nadia Adnan, Rohana Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Nd(C(8)H(3)NO(6))(C(8)H(4)NO(6))(H(2)O)(2)]·2.5H(2)O}(n), the Nd(II) ion is nine-coordinated by seven O atoms from five carboxyl­ate groups and two water mol­ecules. The [Nd(C(8)H(3)NO(6))(H(2)O)(2)](2+) units are bridged by 5-nitro­isophthalate dianions, forming polymeric sheets parallel to the ab plane. The polymeric sheets are linked into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds, and π–π inter­actions [centroid–centroid distance = 3.5533 (11) Å]. The 5-nitro­isophthalate(1−) anion is disordered over three positions with an occupancy ratio of 0.68:0.23:0.09. Two of the uncoordinated water mol­ecules are disordered over two positions, with occupancy ratios of 0.722 (15):0.278 (15) and 0.279 (6):0.221 (6), respectively. International Union of Crystallography 2009-08-22 /pmc/articles/PMC2970002/ /pubmed/21577454 http://dx.doi.org/10.1107/S1600536809032486 Text en © Raime et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Raime, Nurul-Nadia
Adnan, Rohana
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title_full Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title_fullStr Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title_full_unstemmed Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title_short Poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(III)] 2.5-hydrate]
title_sort poly[[diaqua­(3-carb­oxy-5-nitro­ben­zo­ato)(μ-5-nitro­benzene-1,3-dicarboxyl­ato)neodymium(iii)] 2.5-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970002/
https://www.ncbi.nlm.nih.gov/pubmed/21577454
http://dx.doi.org/10.1107/S1600536809032486
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