Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)

In the title mononuclear zinc(II) complex, [Zn(C(8)H(7)O(2)S(2))(2)(C(4)H(6)N(2))(2)], the Zn(II) atom, lying on a twofold axis, is coordinated by two O atoms from two 2-(3,4-disulfanylphen­yl)acetate anions and by two N atoms from 2-methyl­imidazole ligands in a distorted tetra­hdral coordination....

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Detalles Bibliográficos
Autores principales: Wang, Qiang, Wang, Li-Jun, Hou, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970003/
https://www.ncbi.nlm.nih.gov/pubmed/21577482
http://dx.doi.org/10.1107/S1600536809033893
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author Wang, Qiang
Wang, Li-Jun
Hou, Jian
author_facet Wang, Qiang
Wang, Li-Jun
Hou, Jian
author_sort Wang, Qiang
collection PubMed
description In the title mononuclear zinc(II) complex, [Zn(C(8)H(7)O(2)S(2))(2)(C(4)H(6)N(2))(2)], the Zn(II) atom, lying on a twofold axis, is coordinated by two O atoms from two 2-(3,4-disulfanylphen­yl)acetate anions and by two N atoms from 2-methyl­imidazole ligands in a distorted tetra­hdral coordination. The crystal structure is stabilized by inter­molecular C—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions with a centroid–centroid distance of 3.6136 (16) Å.
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spelling pubmed-29700032010-12-30 Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II) Wang, Qiang Wang, Li-Jun Hou, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear zinc(II) complex, [Zn(C(8)H(7)O(2)S(2))(2)(C(4)H(6)N(2))(2)], the Zn(II) atom, lying on a twofold axis, is coordinated by two O atoms from two 2-(3,4-disulfanylphen­yl)acetate anions and by two N atoms from 2-methyl­imidazole ligands in a distorted tetra­hdral coordination. The crystal structure is stabilized by inter­molecular C—H⋯O and N—H⋯O hydrogen bonds and π–π inter­actions with a centroid–centroid distance of 3.6136 (16) Å. International Union of Crystallography 2009-08-29 /pmc/articles/PMC2970003/ /pubmed/21577482 http://dx.doi.org/10.1107/S1600536809033893 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Qiang
Wang, Li-Jun
Hou, Jian
Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title_full Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title_fullStr Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title_full_unstemmed Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title_short Bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1H-imidazole-κN (3))zinc(II)
title_sort bis[2-(3,4-disulfanylphen­yl)acetato]bis­(2-methyl-1h-imidazole-κn (3))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970003/
https://www.ncbi.nlm.nih.gov/pubmed/21577482
http://dx.doi.org/10.1107/S1600536809033893
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AT wanglijun bis234disulfanylphenylacetatobis2methyl1himidazolekn3zincii
AT houjian bis234disulfanylphenylacetatobis2methyl1himidazolekn3zincii

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