Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate

In the title compound, C(16)H(17)ClN(2)O(5), the dihedral angle between the aromatic rings is 77.36 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a planar [r.m.s. deviation = 0.103 (2) Å] five-membered ring, which is oriented at a dihedral angle of 4.84 (4)° with respect to...

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Detalles Bibliográficos
Autores principales: Sheng, Chao, Xu, Qing-Bing, Liu, Yuan-Yuan, Zhu, Hong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970010/
https://www.ncbi.nlm.nih.gov/pubmed/21577532
http://dx.doi.org/10.1107/S1600536809030736
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author Sheng, Chao
Xu, Qing-Bing
Liu, Yuan-Yuan
Zhu, Hong-Jun
author_facet Sheng, Chao
Xu, Qing-Bing
Liu, Yuan-Yuan
Zhu, Hong-Jun
author_sort Sheng, Chao
collection PubMed
description In the title compound, C(16)H(17)ClN(2)O(5), the dihedral angle between the aromatic rings is 77.36 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a planar [r.m.s. deviation = 0.103 (2) Å] five-membered ring, which is oriented at a dihedral angle of 4.84 (4)° with respect to the adjacent benzene ring. In the crystal structure, weak intermolecular C—H⋯π inter­actions are found.
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spelling pubmed-29700102010-12-30 Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate Sheng, Chao Xu, Qing-Bing Liu, Yuan-Yuan Zhu, Hong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(17)ClN(2)O(5), the dihedral angle between the aromatic rings is 77.36 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a planar [r.m.s. deviation = 0.103 (2) Å] five-membered ring, which is oriented at a dihedral angle of 4.84 (4)° with respect to the adjacent benzene ring. In the crystal structure, weak intermolecular C—H⋯π inter­actions are found. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970010/ /pubmed/21577532 http://dx.doi.org/10.1107/S1600536809030736 Text en © Sheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sheng, Chao
Xu, Qing-Bing
Liu, Yuan-Yuan
Zhu, Hong-Jun
Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title_full Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title_fullStr Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title_full_unstemmed Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title_short Methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
title_sort methyl 2-[2-(6-chloro­pyrimidin-4-yl­oxy)phen­yl]-3,3-dimethoxy­propanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970010/
https://www.ncbi.nlm.nih.gov/pubmed/21577532
http://dx.doi.org/10.1107/S1600536809030736
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AT xuqingbing methyl226chloropyrimidin4yloxyphenyl33dimethoxypropanoate
AT liuyuanyuan methyl226chloropyrimidin4yloxyphenyl33dimethoxypropanoate
AT zhuhongjun methyl226chloropyrimidin4yloxyphenyl33dimethoxypropanoate

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