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trans-Dioxidotetra­pyridine­rhenium(V) triiodide

In the title salt, [ReO(2)(C(5)H(5)N)(4)]I(3), the cation and anion are both located on centres of symmetry. The Re(V) atom adopts a trans-ReO(2)N(4) octa­hedral coordination and short intra­molecular C—H⋯O contacts occur within the cation. In the crystal, the cations form layers perpendicular to [1...

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Detalles Bibliográficos
Autores principales: Siczek, Miłosz, Krawczyk, Marta S., Lis, Tadeusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970012/
https://www.ncbi.nlm.nih.gov/pubmed/21577416
http://dx.doi.org/10.1107/S1600536809030724
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author Siczek, Miłosz
Krawczyk, Marta S.
Lis, Tadeusz
author_facet Siczek, Miłosz
Krawczyk, Marta S.
Lis, Tadeusz
author_sort Siczek, Miłosz
collection PubMed
description In the title salt, [ReO(2)(C(5)H(5)N)(4)]I(3), the cation and anion are both located on centres of symmetry. The Re(V) atom adopts a trans-ReO(2)N(4) octa­hedral coordination and short intra­molecular C—H⋯O contacts occur within the cation. In the crystal, the cations form layers perpendicular to [100] and a weak C—H⋯O inter­action links the cations.
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spelling pubmed-29700122010-12-30 trans-Dioxidotetra­pyridine­rhenium(V) triiodide Siczek, Miłosz Krawczyk, Marta S. Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [ReO(2)(C(5)H(5)N)(4)]I(3), the cation and anion are both located on centres of symmetry. The Re(V) atom adopts a trans-ReO(2)N(4) octa­hedral coordination and short intra­molecular C—H⋯O contacts occur within the cation. In the crystal, the cations form layers perpendicular to [100] and a weak C—H⋯O inter­action links the cations. International Union of Crystallography 2009-08-12 /pmc/articles/PMC2970012/ /pubmed/21577416 http://dx.doi.org/10.1107/S1600536809030724 Text en © Siczek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Siczek, Miłosz
Krawczyk, Marta S.
Lis, Tadeusz
trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title_full trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title_fullStr trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title_full_unstemmed trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title_short trans-Dioxidotetra­pyridine­rhenium(V) triiodide
title_sort trans-dioxidotetra­pyridine­rhenium(v) triiodide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970012/
https://www.ncbi.nlm.nih.gov/pubmed/21577416
http://dx.doi.org/10.1107/S1600536809030724
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