1-Benzyl-3-(2-methoxy­phen­yl)imidazolium tetra­fluoro­borate

In the title compound, C(17)H(17)N(2)O(+)·BF(4) (−), the central imidazolium ring makes dihedral angles of 74.58 (9) and 40.10 (6)° with the phenyl and 2-methoxy­phenyl rings, respectively. In the crystal, a strong π–π inter­action is observed between the imidazolium and 2-methoxy­phenyl rings, with...

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Detalles Bibliográficos
Autor principal: Jiang, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970015/
https://www.ncbi.nlm.nih.gov/pubmed/21577584
http://dx.doi.org/10.1107/S1600536809031602
Descripción
Sumario:In the title compound, C(17)H(17)N(2)O(+)·BF(4) (−), the central imidazolium ring makes dihedral angles of 74.58 (9) and 40.10 (6)° with the phenyl and 2-methoxy­phenyl rings, respectively. In the crystal, a strong π–π inter­action is observed between the imidazolium and 2-methoxy­phenyl rings, with a centroid–centroid distance of 3.5115 (15) Å. In addition, C—H⋯F and C—H⋯O hydrogen bonds and C—H⋯π inter­actions involving the ­phenyl ring are observed.

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