Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)

In the title compound, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(4)Cl)(2)]·C(6)H(4)BrCl, the Sn(IV) atom in the tetra­bromidobis(4-chloro­phen­yl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethyl­amino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.4...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Lo, Kong Mun, Mohd Ali, Hapipah, Robinson, Ward T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970020/
https://www.ncbi.nlm.nih.gov/pubmed/21577402
http://dx.doi.org/10.1107/S1600536809030232
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author Lee, See Mun
Lo, Kong Mun
Mohd Ali, Hapipah
Robinson, Ward T.
author_facet Lee, See Mun
Lo, Kong Mun
Mohd Ali, Hapipah
Robinson, Ward T.
author_sort Lee, See Mun
collection PubMed
description In the title compound, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(4)Cl)(2)]·C(6)H(4)BrCl, the Sn(IV) atom in the tetra­bromidobis(4-chloro­phen­yl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethyl­amino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) Å, suggesting weak hydrogen bonding. The 4-bromo­chloro­benzene solvent mol­ecule, which is a bromination by-product from the reaction, is disordered about a twofold rotation axis with approximately equal occupancy.
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spelling pubmed-29700202010-12-30 Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1) Lee, See Mun Lo, Kong Mun Mohd Ali, Hapipah Robinson, Ward T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(4)Cl)(2)]·C(6)H(4)BrCl, the Sn(IV) atom in the tetra­bromidobis(4-chloro­phen­yl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethyl­amino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) Å, suggesting weak hydrogen bonding. The 4-bromo­chloro­benzene solvent mol­ecule, which is a bromination by-product from the reaction, is disordered about a twofold rotation axis with approximately equal occupancy. International Union of Crystallography 2009-08-08 /pmc/articles/PMC2970020/ /pubmed/21577402 http://dx.doi.org/10.1107/S1600536809030232 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, See Mun
Lo, Kong Mun
Mohd Ali, Hapipah
Robinson, Ward T.
Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title_full Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title_fullStr Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title_full_unstemmed Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title_short Bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(IV)–4-bromo­chloro­benzene (1/1)
title_sort bis[4-(dimethyl­amino)pyridinium] tetra­bromidobis(4-chloro­phen­yl)stannate(iv)–4-bromo­chloro­benzene (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970020/
https://www.ncbi.nlm.nih.gov/pubmed/21577402
http://dx.doi.org/10.1107/S1600536809030232
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AT mohdalihapipah bis4dimethylaminopyridiniumtetrabromidobis4chlorophenylstannateiv4bromochlorobenzene11
AT robinsonwardt bis4dimethylaminopyridiniumtetrabromidobis4chlorophenylstannateiv4bromochlorobenzene11

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