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cis-Bis[1-allyl-3-(2-pyrid­yl-κN)thio­ureato-κS]palladium(II)

Yellow plate-like shaped crystals of the title compound, [Pd(C(9)H(10)N(3)S)(2)], were obtained by ligand-exchange reaction between palladium(II) acetyl­acetonate and the corresponding organic reagent at room temperature. The Pd(II) atom shows a slightly distorted square-planar coordination geometry...

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Detalles Bibliográficos
Autores principales: Orysyk, Svitlana, Bon, Volodimir, Pekhnyo, Vasily
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970023/
https://www.ncbi.nlm.nih.gov/pubmed/21577418
http://dx.doi.org/10.1107/S1600536809029262
Descripción
Sumario:Yellow plate-like shaped crystals of the title compound, [Pd(C(9)H(10)N(3)S)(2)], were obtained by ligand-exchange reaction between palladium(II) acetyl­acetonate and the corresponding organic reagent at room temperature. The Pd(II) atom shows a slightly distorted square-planar coordination geometry consisting of two ligand mol­ecules in a cis conformation that bind in their thio­lic tautomeric form. Weak inter­molecular Pd⋯H inter­actions with Pd—H distances of 3.328 (2) Å were observed in the crystal structure. The three-dimensional network of the crystal structure is realized by weak inter­molecular C—H⋯N, N—H⋯N and C—H⋯S hydrogen bonds.